Liquid Metal Circuits With Alloyed Traces for Stretchable Conductivity

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Solution Overview

Problem

Conventional stretchable electronics based on soft-elastomers with percolating networks of rigid metallic particles or conductive polymers suffer from low conductivity and poor electromechanical properties, limiting their power-carrying capacity and reproducibility in manufacturing.

Innovation Solution

The development of liquid metal circuits coated on elastic substrates using metallic alloying, which provides self-healing properties and high conductivity, integrated with traditional electronic components for enhanced robustness and flexibility, utilizing techniques like dip-coating and vapor state reduction agents for improved electrical contact and alignment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional stretchable electronics use soft-elastomers with percolating networks of rigid metallic particles or conductive polymers, then the devices achieve flexibility and stretchability, but the conductivity and power-carrying capacity are severely limited

Engineering Contradiction:
Improveflexibility and stretchabilityVSAvoidconductivity and power-carrying capacity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the physical state of the conductive material from solid (rigid particles) to liquid (gallium-based alloy), enabling the conductor to flow and redistribute under mechanical deformation while maintaining high conductivity. This parameter change resolves the contradiction by allowing the material to be both highly conductive and mechanically compliant.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite system combining liquid metal alloy with elastomeric encapsulation, integrating the high conductivity of liquid metal with the flexibility and stretchability of soft elastomers. This composite approach allows simultaneous achievement of both electrical performance and mechanical compliance.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If micro/nanoscale geometries of ultrathin conductive elements are used to achieve stretchability through flexure or twisting, then the devices gain deformability, but the power-carrying capacity is severely limited

Engineering Contradiction:
ImprovedeformabilityVSAvoidpower-carrying capacity
Core Design Contradiction:
Adaptability or versatilityVSPower

Solution Approach 1:

The patent transitions from ultrathin solid conductors to liquid metal conductors with可调 geometry. The liquid metal can form thicker, more robust conductive pathways while maintaining deformability, as the liquid state allows the material to flow and redistribute rather than fracture under mechanical stress.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If deterministic architectures with specific geometries (prebuckled waves, planar serpentines) are used for stretchability, then the devices achieve controlled deformability, but manufacturing reproducibility and throughput are reduced

Engineering Contradiction:
Improvecontrolled deformabilityVSAvoidmanufacturing reproducibility and throughput
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent changes the geometric constraints from fixed deterministic patterns to fluid adaptable configurations. The liquid metal can be deposited as continuous layers that naturally conform to substrate deformation without requiring precise pre-patterning, significantly simplifying manufacturing while maintaining stretchability.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If conventional fabrication methods are used for stretchable electronics, then the manufacturing process is established, but reproducibility and throughput remain limited

Engineering Contradiction:
Improveestablished fabrication processVSAvoidreproducibility and throughput
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent employs liquid metal deposition techniques analogous to hydraulic principles, where the liquid alloy flows and distributes according to pressure and surface energy gradients. This enables simple, scalable deposition processes such as dip-coating or spray deposition that can be easily implemented with high throughput and reproducibility.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high reproducibility and throughput in manufacturing stretchable electronics with maintained conductivity under mechanical deformation, enabling flexible integration of rigid and flexible components for diverse applications.

Implementation Method 1

applying a liquid metal to an alloying metal pattern on an elastic substrate to form the liquid metal circuit

Methodology Applied
Scientific EffectMetallic alloying:

Implementation Method 2

exposing the microelectronic component and the liquid metal trace to a solvent gas to remove oxide from at least one of the microelectronic component and the liquid metal trace

Methodology Applied
Scientific EffectOxide removal by vapor state reduction agent: Reduction

Data Source

PatentUS11805597B2Liquid metal circuits and methods of making the same
Publication Date: 2023.10.31 THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE NAVY
  • US11805597B2 patent drawing
  • US11805597B2 patent drawing
  • US11805597B2 patent drawing

AI summary

A high-throughput method of manufacturing a liquid metal circuit may include applying a liquid metal to an alloying metal pattern on an elastic substrate to form the liquid metal circuit. The elastic substrate may have a surface area greater than 1 square inch. The liquid metal circuit may include a plurality of liquid metal circuits on the elastic substrate. Methods of using the liquid metal circuit are also described.