Liquid-Piston Gas Cooling for Isentropic Hydrogen Expansion

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Solution Overview

Problem

Current hydrogen refueling stations require additional chillers to cool hydrogen due to isenthalpic expansion at the proportional valve, increasing energy consumption and costs, and existing solutions are inefficient and costly.

Innovation Solution

A device utilizing a piston chamber with a liquid piston and damping system to achieve isentropic expansion, dynamically controlling pressure and removing heat, potentially replacing the need for a pressure ramp regulator and chiller.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If isenthalpic expansion at proportional valve is used for pressure regulation, then pressure control is achieved, but significant heat is released causing gas temperature to exceed maximum permissible limits

Engineering Contradiction:
Improvepressure controlVSAvoidgas temperature
Core Design Contradiction:
Stress or pressureVSTemperature

Solution Approach 1:

The patent changes the thermodynamic parameters of the expansion process from isenthalpic (constant enthalpy) to isentropic (constant entropy) by using a piston-cylinder mechanism with controlled expansion. This parameter change allows pressure regulation while minimizing temperature increase, solving the contradiction between pressure control and temperature management.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional proportional valve (pneumatically or magnetically actuated) with a mechanically controlled piston system. This mechanical substitution enables isentropic expansion through controlled piston movement, achieving pressure regulation without the significant heat release characteristic of valve-based isenthalpic expansion.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Temperature

If additional chiller is used to cool the gas after expansion, then temperature is reduced to acceptable levels, but electrical energy consumption increases

Engineering Contradiction:
Improvegas temperatureVSAvoidelectrical energy consumption
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

The patent performs cooling action during the expansion process itself rather than as a subsequent separate step. The isentropic expansion mechanism inherently limits temperature rise, and the piston system performs preliminary cooling work during expansion, eliminating or reducing the need for additional post-expansion chilling and associated energy consumption.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the harmful heat release during expansion into a beneficial controlled process. By using isentropic expansion with a piston system, the expansion work itself contributes to cooling the gas, transforming what would be a harmful thermal effect into a useful cooling mechanism that reduces or eliminates the need for additional energy-consuming chillers.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Temperature

If compression chiller is used to remove heat during expansion, then cooling is achieved, but device complexity and installation costs increase

Engineering Contradiction:
Improveheat removalVSAvoidequipment requirements
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent merges the expansion mechanism and cooling function into a single integrated piston-cylinder system. The isentropic expansion process inherently performs the cooling function, eliminating the need for separate compression chillers and reducing overall device complexity while achieving the required temperature management.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The expansion system serves its own cooling needs through the isentropic expansion process. The piston mechanism automatically performs the cooling function during expansion without requiring external cooling equipment, making the system self-sufficient and reducing overall equipment requirements.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly reduces cooling capacity requirements by 50-100%, offering a cost-effective and durable solution with reduced energy consumption and environmental impact.

Implementation Method 1

The functioning of the device according to the invention for cooling a gas, preferably hydrogen, is based on the principle of so-called isentropic expansion, in which work is taken away from the gas in order to cool it down.

Methodology Applied
Scientific EffectIsentropic expansion: Adiabatic Cooling

Implementation Method 2

means for removing heat from the piston chamber and/or damping system

Methodology Applied
Scientific EffectHeat removal: Heat Sink

Data Source

PatentEP4641069A1Device for cooling a gas
Publication Date: 2025.10.29 LINDE AG
  • EP4641069A1 patent drawing
  • EP4641069A1 patent drawing
  • EP4641069A1 patent drawing

AI summary

A device for cooling a gas and a hydrogen filling station, comprising at least one device according to the invention, are described. The device comprises the following: a piston chamber (2); a liquid piston (3) arranged in the piston chamber (2); a supply line (1) associated with the first end (9) of the piston chamber (2) and having an inlet valve (b); a discharge line (10) associated with the first end (9) of the piston chamber (2) and having an outlet valve (b); a piston (4) associated with the second end of the piston chamber (2); a damping system associated with the piston (4); a control unit (8) that is operatively connected to the damping system and dynamically regulates the pressure to be applied to the piston (4); and means for dissipating heat from the piston chamber (2) and/or damping system.