Liquid Resin Composition for Low-Viscosity Power Module Encapsulation

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Solution Overview

Problem

Existing liquid encapsulating materials for power semiconductor elements face challenges with high viscosity, sedimentation of inorganic fillers, and reduced reliability due to cracking, which affects the heat resistance and workability of the encapsulating resin.

Innovation Solution

A liquid resin composition is developed that includes an epoxy resin with an alicyclic epoxy resin, an acid anhydride, a curing accelerator, an inorganic filler, and a sedimentation preventing agent, which maintains low viscosity and reduces filler sedimentation, ensuring excellent workability and heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If inorganic filler is added to reduce linear expansion coefficient, then heat resistance is improved, but viscosity increases and workability deteriorates

Engineering Contradiction:
Improveheat resistanceVSAvoidworkability of casting
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent changes the chemical composition parameters of the epoxy resin system by selecting specific epoxy resins with appropriate viscosity and reactivity, and matching them with corresponding curing agents and accelerators. This parameter optimization allows the resin to maintain low viscosity even with high inorganic filler content (65-85% by mass), resolving the contradiction between heat resistance and workability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining epoxy resin, curing agent, curing accelerator, and inorganic filler in specific proportions. This composite approach allows the synergistic effect of components to maintain low viscosity while achieving high heat resistance through the inorganic filler, thus resolving the technical contradiction

Inventive Principle:
Principle #40Composite materials

2Temperature

If inorganic filler is added to reduce linear expansion coefficient, then heat resistance is improved, but sedimentation occurs during curing and reliability decreases

Engineering Contradiction:
Improveheat resistanceVSAvoidcrack resistance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent introduces a coupling agent as an intermediary substance that chemically bonds between the inorganic filler particles and the epoxy resin matrix. This coupling agent prevents filler sedimentation during curing by creating strong interfacial adhesion, thereby maintaining material homogeneity and preventing cracks that would reduce reliability, while still allowing high filler content for heat resistance

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the particle size distribution and surface treatment parameters of the inorganic filler to prevent sedimentation. By controlling these parameters and matching them with appropriate curing accelerators, the resin maintains homogeneity during curing, preventing the formation of weak zones that would lead to cracking

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If inorganic filler content is increased to reduce linear expansion, then thermal stability is improved, but viscosity increases and casting workability deteriorates

Engineering Contradiction:
Improvelinear expansion coefficientVSAvoidviscosity
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent carefully controls the particle size, shape, and surface characteristics of the inorganic filler, and optimizes the viscosity and molecular weight of the epoxy resin. These parameter changes allow high filler content (65-85% by mass) to be achieved while maintaining low viscosity and excellent casting workability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality optimization by using filler particles with specific surface treatments and size distributions in different regions of the composition. This localized optimization ensures uniform dispersion and low viscosity throughout the material, while achieving the desired low linear expansion coefficient

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin composition achieves excellent workability, reduced sedimentation of inorganic fillers, and enhanced heat resistance, resulting in a power device with improved crack resistance, electrical, mechanical, and thermal properties.

Implementation Method 1

a sedimentation preventing agent... reduces sedimentation of the inorganic filler during storage

Methodology Applied
Scientific EffectSedimentation prevention: Suspension

Implementation Method 2

the epoxy resin (A) includes an alicyclic epoxy resin, and a viscosity of the liquid resin composition at 25°C is 75 Pa·s or less

Methodology Applied
Scientific EffectViscosity reduction:

Implementation Method 3

an encapsulating material for a power module is required to have low linear expansion... In order to reduce the coefficient of linear expansion, it is common practice to add an inorganic filler

Methodology Applied
Scientific EffectThermal expansion reduction: Thermal Expansion

Implementation Method 4

the liquid resin composition containing: (A) an epoxy resin; (B) an acid anhydride

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP4535417A1Liquid resin composition and resin-encapsulated power module
Publication Date: 2025.04.09 SUMITOMO BAKELITE CO LTD
  • EP4535417A1 patent drawing
  • EP4535417A1 patent drawing
  • EP4535417A1 patent drawing

AI summary

Provided is a liquid resin composition used for encapsulating, by a casting method, a power module which includes a substrate for a power module, over which a circuit layer is formed, and a power semiconductor element mounted over the circuit layer of the substrate for a power module, the liquid resin composition containing (A) an epoxy resin, (B) an acid anhydride, (C) a curing accelerator, (D) an inorganic filler, and (E) a sedimentation preventing agent, in which the epoxy resin (A) includes an alicyclic epoxy resin, and a viscosity of the liquid resin composition at 25°C is 75 Pa·s or less.