Liquid Solvent Treatment for Polymer Volatile Removal

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Solution Overview

Problem

Current processes for treating plastic materials with steam or inert gas at elevated temperatures are inefficient in removing volatile components, leading to persistent emissions, taste, and odor issues, particularly in applications like drinking water pipes and automobile parts, and result in the generation of unwanted fines and streamers during conveying.

Innovation Solution

A process using a liquid solvent at a temperature below its boiling point to contact and treat plastic materials, allowing for efficient removal of volatile components without the need for massive air or inert gas, reducing energy consumption, and minimizing the generation of fines and streamers, with water being a preferred solvent due to its low solubility of monomers and hydrocarbons.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If steam or inert gas at elevated temperature is used to treat plastic material, then volatile components are removed to some extent, but removal efficiency is insufficient and emissions, taste and odor are not sufficiently improved

Engineering Contradiction:
Improvevolatile component removalVSAvoidemissions, taste and odor
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent changes the physical state parameter of the treatment medium from gas (steam or inert gas) to liquid (water). This parameter change enables much more efficient removal of volatile components from plastic pellets. The liquid water phase allows for superior contact and extraction of volatile substances compared to gas phase, thereby significantly reducing emissions, taste, and odor problems.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs hydraulic principles by using liquid water instead of pneumatic methods (steam or inert gas). The liquid phase provides better hydraulic contact with the plastic pellets, enabling more effective removal of volatile components. This hydraulic approach fundamentally improves the treatment efficiency compared to traditional pneumatic methods.

Inventive Principle:
Principle #29Pneumatics and hydraulics

2Quantity of substance

If hot polymer pellets are pneumatically conveyed for removing volatile components, then treatment can be performed, but generation of unwanted fines and streamers occurs due to friction

Engineering Contradiction:
Improvevolatile component removalVSAvoidfines and streamers
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent replaces pneumatic conveying with hydraulic conveying using liquid water. Instead of using gas flow to transport and treat the pellets, the invention uses liquid water as both the treatment medium and conveying medium. This eliminates the high-velocity gas-particle interactions that cause friction, preventing the generation of fines and streamers while maintaining effective volatile component removal.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Productivity

If steam is used for removing volatile components, then treatment efficiency is improved, but handling becomes more difficult and additional condensation equipment is required

Engineering Contradiction:
Improvevolatile component removal efficiencyVSAvoidhandling safety and complexity
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent uses liquid water, which is inexpensive and readily available, replacing expensive and complex steam generation and handling systems. Water can be easily pumped, distributed, and disposed of or recycled without requiring complex condensation equipment. This principle of using simple, inexpensive media (liquid water) instead of complex systems (steam generation and condensation infrastructure) significantly improves ease of operation while maintaining or enhancing treatment efficiency.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Quantity of substance

If massive amounts of air or inert gas are used for removing volatile components, then removal efficiency is improved, but energy consumption increases

Engineering Contradiction:
Improvevolatile component removalVSAvoidenergy consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent replaces pneumatic methods requiring massive gas flows with hydraulic methods using liquid water. The liquid phase provides much higher density and better contact efficiency, achieving superior volatile component removal with minimal water consumption. This eliminates the need for energy-intensive gas generation, heating, and circulation systems, dramatically reducing energy consumption while improving removal efficiency.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively removes a high percentage of volatile components, improving energy efficiency and reducing emissions, while avoiding the need for additional drying steps and costly safety precautions, achieving significant reductions in volatile content within a short treatment time.

Implementation Method 1

contacting plastic material with a solvent in liquid form... the use of a liquid instead of steam according to the invention not only removes volatile components more efficiently from the plastic material

Methodology Applied
Scientific EffectExtraction: Liquid-Liquid Extraction

Implementation Method 2

The volatile components comprise monomers, hydrocarbons and hydrocarbon derivatives... The process particularly removes volatile components containing 2 to 20 carbon atoms

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

In the inventive process and plant vaporized liquid may be used to heat the liquid, whereby the amount of vaporized liquid which has to be recondensed is much less compared with prior art processes

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

Energy savings additionally originate from the facilitated heat transfer from liquid to solid plastic material compared to the heat transfer from gas to solid plastic material

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentEP2072203B2Removing volatile compounds from polymer pellets
Publication Date: 2020.11.18 BOREALIS TECH OY
  • EP2072203B2 patent drawingFigure 1
  • EP2072203B2 patent drawingFigure 2
  • EP2072203B2 patent drawingFigure 3

AI summary

The invention is directed to a process for the treatment of plastic material comprising a) providing a liquid; b) contacting the plastic material with the liquid; c) keeping the plastic material in the liquid at Tb-25 °C to Tb of the liquid, wherein Tb is the boiling point of the liquid at the applied pressure; and d) removing the plastic material from the liquid. Furthermore, the invention is directed to the use of a liquid for the treatment of plastic material and to a plant for treating plastic material with a liquid.