Liquid Stabilizer Mixture for Polymers

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Solution Overview

Problem

Existing stabilizers for inanimate organic materials, particularly plastics, often face challenges in handling, miscibility, and concentration when trying to protect against light, oxygen, and heat, as they are typically solid powders that are difficult to incorporate homogeneously and require additional steps for dispersion or dissolution, leading to lower effective concentrations and transportation issues.

Innovation Solution

Development of liquid mixtures comprising one or more liquid UV absorbers and branched polymers with stabilizing groups, which are easy to handle, incorporate, and maintain high concentrations, providing efficient stabilization against light, oxygen, and heat without volatility and migration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If solid powder stabilizers are used, then high stabilizer concentration can be achieved, but handling and incorporation become difficult requiring additional dispersion steps

Engineering Contradiction:
Improvestabilizer concentrationVSAvoidhandling and incorporation ease
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent changes the physical state parameter of the stabilizer from solid powder to liquid form. This parameter change resolves the contradiction by providing ease of handling and incorporation like liquids while maintaining high effective concentration through the specific liquid composition and molecular structure design.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite liquid stabilizer system combining multiple components (UV absorbers, HALS compounds, phenolic antioxidants, and polymer carriers) into a single liquid mixture. This composite approach allows the stabilizer to maintain high effectiveness while being easily incorporated as a liquid, eliminating the need for separate dispersion steps.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If solid powder stabilizers are used, then high stabilizer concentration can be achieved, but homogeneous incorporation requires additional dispersion or dissolution steps

Engineering Contradiction:
Improvestabilizer concentrationVSAvoidhomogeneous incorporation
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

Changing the physical state from solid to liquid eliminates the need for dispersion or dissolution steps. The liquid stabilizer mixes homogeneously with the polymer matrix through simple blending, achieving uniform distribution without additional manufacturing complexity while maintaining high effective concentration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses liquid polymer carriers and solvents as intermediaries to facilitate homogeneous incorporation. These liquid media allow the stabilizer components to distribute uniformly throughout the polymer matrix during processing, ensuring consistent protection without requiring complex dispersion equipment or procedures.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If liquid stabilizers are used, then ease of handling and incorporation improves, but stabilizer concentration tends to be lower

Engineering Contradiction:
Improvehandling and incorporation easeVSAvoidstabilizer concentration
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent formulates a composite liquid system where high-boiling-point polymer carriers and concentrated stabilizer components work together. This composite structure allows the liquid stabilizer to maintain high effective concentration (comparing favorably with solid powder formulations) while preserving the handling and incorporation advantages of liquid form.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent carefully selects and adjusts parameters of the liquid components including molecular weight, boiling point, and chemical structure of the polymer carriers and UV absorbers. These parameter optimizations ensure that the liquid stabilizer achieves both ease of handling and high effective concentration, resolving the apparent trade-off between these two properties.

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If liquid stabilizers are used, then incorporation ease improves, but volatility and migration become concerns

Engineering Contradiction:
Improveincorporation easeVSAvoidstability against volatility and migration
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent selects liquid components with specifically optimized parameters including high boiling points and appropriate molecular weights. These parameter choices ensure that the liquid stabilizer incorporates easily into the polymer matrix while maintaining sufficient thermal and chemical stability to prevent volatility and migration under normal use conditions, thus resolving the contradiction between ease of incorporation and long-term stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The liquid mixtures effectively stabilize materials against degradation from light, oxygen, and heat, offering improved handling and incorporation ease while maintaining high stabilizer concentrations and reducing transportation challenges.

Implementation Method 1

one or more liquid UV absorbers

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Implementation Method 2

branched polymers comprising stabilizing groups

Methodology Applied
Scientific EffectFree radical scavenging: Absorption (physical)

Data Source

PatentUS8680183B2Liquid stabilizer mixture
Publication Date: 2014.03.25 BASF SE
  • US8680183B2 patent drawing
  • US8680183B2 patent drawing
  • US8680183B2 patent drawing

AI summary

A mixture comprising(a) one or more liquid UV absorbers, with the proviso that Tinuvin 384-2 as a liquid UV absorber is excluded,(b) one or more branched polymers comprising stabilizing groups,(c) optionally one or more further additions.Use of such a mixture for stabilizing inanimate organic materials against the effect of light, oxygen and/or heat. Inanimate organic materials comprising at least one such mixture, and also articles produced from such inanimate organic materials. Methods of stabilizing inanimate organic materials against the effect of light, oxygen and/or heat by adding to said inanimate organic materials at least one such mixture in an effective amount.