Lithium Passivation Regions for Neutron Target Diffusion Control

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Solution Overview

Problem

Existing methods for protecting lithium in neutron generation devices are inadequate, as they either fail to control lithium diffusion, lead to rapid oxidation, or reduce neutron yield due to thick coatings, and are costly or hazardous to handle.

Innovation Solution

A passivation region is configured to inhibit lithium diffusion and protect it from ambient substances, using materials like lithium fluoride and aluminum to form a multi-layer barrier that maintains lithium's integrity and neutron generation capability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a thick layer of lithium is covered by a thin layer of stainless steel, then the lithium is protected from oxidation, but the protection time is limited to only 10 minutes

Engineering Contradiction:
Improveprotection effectivenessVSAvoidprotection duration
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent uses a composite passivation region comprising multiple layers with different functions: a first passivation layer (e.g., aluminum) that provides immediate protection and a second passivation layer (e.g., lithium fluoride) that provides long-term protection. This multi-layer composite structure resolves the contradiction by combining materials with complementary properties to achieve both immediate and sustained protection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The passivation protection is segmented into multiple functional layers rather than using a single thick coating. The first passivation layer handles initial protection needs while the second layer provides extended protection, allowing each layer to be optimized for its specific function and time period.

Inventive Principle:
Principle #1Segmentation

2Reliability

If a thick coating is applied on top of accelerator target materials, then the target material is protected, but the accelerator particles are slowed down resulting in lower yield or prevention of desired reaction

Engineering Contradiction:
Improveprotection effectivenessVSAvoidneutron generation yield
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent employs thin film passivation layers that provide adequate protection while minimizing interference with accelerator particle penetration. The thin film structure allows particles to pass through with minimal energy loss, maintaining reaction yield while still providing effective protection.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The passivation layers are applied with specific thickness control and material selection optimized for the local requirements: the first layer provides immediate protection at the surface, while the second layer provides sustained protection, with each layer's thickness and composition tailored to balance protection needs with particle penetration requirements.

Inventive Principle:
Principle #3Local quality

3Reliability

If lithium is handled in a dry room to prevent oxidation, then oxidation is reduced, but construction is complicated and expensive, and moisture from humans eliminates benefits

Engineering Contradiction:
Improveoxidation preventionVSAvoidfacility complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The passivation layers are applied in advance to the lithium target material before it is exposed to ambient conditions. This preliminary protective action eliminates the need for complex dry room facilities, as the lithium is already protected when handled in normal environments.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The passivation layers act as intermediary barriers between the lithium and the ambient environment. These intermediate layers prevent direct contact between lithium and oxidizing substances, allowing handling in normal conditions without requiring specialized dry room infrastructure.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If lithium is handled in a glovebox filled with inert gas, then oxidation is prevented, but transfer to working area requires complex dry room facilities

Engineering Contradiction:
Improveoxidation preventionVSAvoidtransfer ease
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The passivation layers are applied beforehand to the lithium, allowing it to be transferred from the glovebox to the working area without requiring dry room facilities. The preliminary protection enables straightforward transfer and handling in normal environments.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The passivation layers serve as intermediary protective barriers that allow lithium to be handled in ambient conditions. This intermediary protection eliminates the need for complex transfer procedures between controlled environments, simplifying the operational workflow.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The passivation region effectively prevents lithium oxidation and diffusion, maintaining neutron generation efficiency and simplifying handling, while extending the protected period to several months.

Implementation Method 1

A passivation region is configured to seal against diffusion of a material of a neutron generation region into and/or through the passivation region

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

The passivation region can also be configured to seal against diffusion of an externally sourced or ambient substance into and/or through the passivation region towards the underlying region

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS12446142B2Materials and configurations for protection of objective materials
Publication Date: 2025.10.14 TAE TECHNOLOGIES INC
  • US12446142B2 patent drawing
  • US12446142B2 patent drawing
  • US12446142B2 patent drawing

AI summary

Passivation regions and device configurations are described herein. The passivation regions can be configured to seal against diffusion of an objective material from an underlying region into and/or through the passivation region. The passivation regions can also be configured to seal against diffusion of an externally sourced or ambient substance into and/or through the passivation region towards the underlying region.