Lithium Selective Permeable Membrane for High-Speed Recovery

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Solution Overview

Problem

Current lithium recovery devices have a high installation and operation cost, and the recovery speed of lithium ions from raw to recovery liquid is not sufficient to meet the required low production cost, especially when used on a large scale.

Innovation Solution

A lithium selective permeable membrane with a lithium ion conductor and a lithium adsorption layer formed by acid treatment, used in a lithium recovery device that separates raw and recovery liquids with electrodes, enhancing ion conductivity and recovery efficiency through pH conversion and electrodialysis.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If lithium recovery devices are installed and used on a large scale, then the total amount of lithium recovered increases, but the installation and operation cost increases

Engineering Contradiction:
Improvetotal amount of lithium recoveredVSAvoidinstallation and operation cost
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameter of the selective permeable membrane by forming a lithium adsorption layer through acid treatment, which fundamentally alters the membrane's ion selectivity properties. This enables high-speed lithium recovery while maintaining cost-effectiveness through improved recovery efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure combining a base selective permeable membrane with a lithium adsorption layer formed by acid treatment. This composite material achieves both high lithium selectivity and high recovery speed, resolving the contradiction between large-scale recovery needs and operational costs

Inventive Principle:
Principle #40Composite materials

2Productivity

If the recovery speed of lithium ions is increased to meet production cost requirements, then the production cost decreases, but the selectivity or efficiency of the membrane may be compromised

Engineering Contradiction:
Improverecovery speedVSAvoidselectivity of membrane
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality modification by treating only the surface of the selective permeable membrane with acid to form a lithium adsorption layer. This localized treatment enhances lithium recovery speed at the membrane surface while preserving the bulk membrane's selective permeability properties

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The acid treatment is performed in advance to pre-form the lithium adsorption layer on the membrane surface before actual lithium recovery operations begin. This preliminary action ensures the membrane is optimized for high-speed recovery from the start, meeting production cost requirements

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly increases the recovery rate of lithium ions into the recovery liquid, achieving a high recovery efficiency and reducing production costs by improving the recovery speed and ion conductivity.

Implementation Method 1

a selective permeable membrane main body constituted of a ion conductor of lithium as a main body

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 2

a lithium adsorption layer that is formed on a surface of the selective permeable membrane main body on the first main surface side and selectively adsorbs the lithium ions

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

the lithium adsorption layer is formed by an acid treatment on the surface of the selective permeable membrane main body

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

Li (ions) in the raw liquid is moved in the recovery liquid by applying a voltage between both electrodes

Methodology Applied
Scientific EffectElectrodialysis: Electrophoresis

Data Source

PatentUS10689766B2Lithium selective permeable membrane, lithium recovery device, lithium recovery method, and hydrogen production method
Publication Date: 2020.06.23 NAT INST FOR QUANTUM & RADIOLOGICAL SCI & TECH
  • US10689766B2 patent drawing
  • US10689766B2 patent drawing
  • US10689766B2 patent drawing

AI summary

The disclosure relates to recovering Li ions in a raw liquid into a recovery liquid at a high recovery speed. A lithium selective permeable membrane is constituted of a selective permeable membrane main body constituted of a lithium ion superconductor (ion conductor) having a particularly high ion conductivity and a Li adsorption layer formed as a thin layer on a raw liquid side (a first electrode) thereof. As a material constituting the selective permeable membrane main body, specifically, lanthanum lithium titanium oxide can be used. The Li adsorption layer is formed as a thin layer on a surface of the selective permeable membrane main body by carrying out a chemical treatment on the selective permeable membrane main body.