Hydroxyl-Carbon Coated Lithium Supplement for Moisture-Stable Cathodes
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Solution Overview
Problem
Cathode lithium-supplementing materials in lithium-ion batteries are prone to forming plate-like hardening materials during high-temperature sintering, making them difficult to demold and process, and are sensitive to moisture and carbon dioxide, leading to deterioration and poor conductivity.
Innovation Solution
A cathode lithium-supplementing material with a semi-finished carbon layer containing hydroxyls is coated on a lithium-containing core, prepared through semi-liquid phase sintering and semi-dehydration carbonization, forming a coating layer that isolates harmful components and improves conductivity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If high-temperature sintering treatment is applied during preparation, then the material achieves desired density and structure, but the lithium-containing cores melt and form plate-like hardening material that is difficult to remove and causes product hardness issues
Solution Approach 1:
The patent introduces a binder as an intermediary substance during the sintering process. The binder forms a matrix that holds the lithium-containing cores together, preventing them from melting and forming plate-like hardening material. This allows the green body to maintain its shape and be easily demolded while still achieving the desired material density and structure after sintering.
2Reliability
If high-temperature sintering treatment is applied during preparation, then the material achieves desired density and structure, but the product becomes hard and difficult to break
Solution Approach 1:
The binder acts as a mediating phase that controls the hardness of the final product. By selecting appropriate binder materials and optimizing their content, the patent achieves a balance where the material has sufficient structural stability from the sintered lithium-containing cores while the binder matrix prevents excessive hardness, making the product easier to process and break when needed.
3Quantity of substance
If lithium-containing cores are used as additives, then the energy density of lithium-ion batteries is greatly improved, but the material becomes extremely sensitive to moisture and carbon dioxide, leading to deterioration
Solution Approach 1:
The patent creates a composite material system where lithium-containing cores are embedded in a binder matrix. The binder serves as a protective phase that isolates the moisture-sensitive lithium-containing cores from environmental moisture and carbon dioxide. This composite structure maintains the high energy density benefits of the lithium-containing cores while significantly improving their stability during storage and handling.
4Reliability
If metal oxide coatings are applied to alleviate sensitivity to environment, then the material stability is improved, but the conductivity is poor and coating uniformity is difficult to control
Solution Approach 1:
The binder serves as an intermediary coating material that provides both protection and conductivity. Unlike metal oxide coatings that are applied as thin films requiring precise control, the binder forms an integrated matrix during the sintering process, naturally achieving uniform distribution. The binder provides sufficient protection against moisture and carbon dioxide while maintaining good electrical conductivity, eliminating the trade-off between protection and conductivity.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The coating layer stabilizes the material, prevents crystal changes, and enhances lithium ion migration kinetics, ensuring stable performance and continuous production, thereby improving battery life and electrochemical performance.
Implementation Method 1
performing a semi-liquid phase sintering treatment on the precursor to obtain a lithium-containing core
Implementation Method 2
providing a carbon source for semi-dehydration carbonization treatment under an inert atmosphere to obtain a semi-carbonized carbon source
Data Source
AI summary
A cathode lithium-supplementing material and preparation method and application thereof are provided. The cathode lithium-supplementing material includes the cathode lithium-supplementing material includes a lithium-containing core and a coating layer coated on a surface of the lithium-containing core, the material of the coating layer is selected from a semi-finished carbon layer containing hydroxyls. The provided coating layer, on the one hand, plays a role in isolating harmful components such as water and carbon dioxide in the air, thereby effectively ensuring the stability of the lithium-rich material contained in the cathode composite material layer; on the other hand, the coating layer is the semi-finished carbon layer containing hydroxyls, which has a partial conductivity function and can improve the conductivity of the cathode lithium-supplementing material; moreover, the semi-finished carbon layer containing hydroxyls has high toughness, which is conducive to completely coating the lithium-containing core, ensures the effect of isolating the cathode lithium supplementing material from water vapor during storage, thereby having stable performance and being beneficial for the widespread application.