Lithium Titanate-Coated Composite Anode for Reduced Side Reactions

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Solution Overview

Problem

Lithium ion batteries using transition metal oxides as anode electrode materials exhibit poor capacity retention rates after cycling due to limited electrical conductivity and susceptibility to side reactions with electrolytes, as well as volume expansion issues.

Innovation Solution

A composite anode electrode material is developed by coating or doping defect-type transition metal oxides with lithium titanate, which improves electrical conductivity and structural stability, reducing the likelihood of side reactions and volume expansion, thereby enhancing capacity retention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If transition metal oxide is used as anode electrode material to improve theoretical capacity, then capacity is improved, but electrical conductivity deteriorates

Engineering Contradiction:
Improvetheoretical capacityVSAvoidelectrical conductivity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses composite materials by combining defect-type transition metal oxide with conductive carbon materials (such as graphite, carbon nanotubes, or conductive polymer) to create a composite anode electrode material. The carbon component provides the necessary electrical conductivity while the transition metal oxide provides high theoretical capacity, thus resolving the contradiction between capacity improvement and conductivity deterioration.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces conductive carbon materials as an intermediary substance between the transition metal oxide particles and the electrolyte. This intermediary layer improves electron transport pathways while allowing lithium ion insertion/extraction, thereby enhancing electrical conductivity without compromising the high capacity benefits of the transition metal oxide.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If defect-type transition metal oxide is used to improve conductivity, then electrical conductivity is improved, but chemical activity increases causing side reactions with electrolyte

Engineering Contradiction:
Improveelectrical conductivityVSAvoidside reactions with electrolyte
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces conductive carbon materials as a protective intermediary layer that coats or surrounds the defect-type transition metal oxide particles. This carbon layer acts as a barrier that prevents direct contact between the highly active transition metal oxide surface and the electrolyte, thereby suppressing side reactions while maintaining the improved electrical conductivity provided by the defect structure and carbon matrix.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The conductive carbon material creates an inert chemical environment around the transition metal oxide particles, shielding them from direct interaction with the electrolyte. This inert carbon layer prevents unwanted chemical reactions while allowing electrical conduction and lithium ion transport, thus resolving the contradiction between improved conductivity and reduced side reactions.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Quantity of substance

If silicon-based material is used to improve theoretical capacity, then capacity is improved, but volume expansion causes structural damage and poor cycle performance

Engineering Contradiction:
Improvetheoretical capacityVSAvoidstructural stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent employs conductive carbon materials as flexible shell structures that encapsulate the transition metal oxide particles. These carbon shells provide mechanical flexibility to accommodate volume changes during lithium ion insertion and extraction cycles, preventing structural damage and pulverization while maintaining electrical conductivity and structural integrity over multiple cycles.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent creates a composite structure where transition metal oxide particles are embedded in a carbon matrix or coated with carbon shells. This composite design combines the high capacity of transition metal oxide with the structural stability and flexibility of carbon materials, allowing the anode to withstand volume expansion and contraction during cycling without losing structural integrity.

Inventive Principle:
Principle #40Composite materials

4Stability of the object's composition

If graphite material is used as anode electrode material to ensure structural stability, then structural stability is maintained, but lithium ion accommodation ability deteriorates

Engineering Contradiction:
Improvestructural stabilityVSAvoidlithium ion accommodation ability
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent creates a composite anode electrode material that combines graphite's structural stability with transition metal oxide's high lithium ion accommodation ability. The composite structure allows graphite to provide a stable framework while transition metal oxide particles contribute high capacity through multiple lithium ion insertion sites, thus achieving both structural stability and enhanced lithium ion accommodation.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite anode electrode material demonstrates improved electrical performance and stability, with a higher capacity retention rate after cycling, by balancing conductivity and chemical activity through the use of lithium titanate coating and doping.

Implementation Method 1

lithium titanate is compounded with the defect-type transition metal oxide in the manner of coating and/or doping... improved electrical performance and stability

Methodology Applied
Scientific EffectCharge transfer:

Implementation Method 2

lithium titanate is compounded with the defect-type transition metal oxide in the manner of coating and/or doping

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 3

lithium titanate is compounded with the defect-type transition metal oxide in the manner of coating and/or doping... reducing the likelihood of side reactions

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 4

lithium ions move back and forth between a positive electrode and an anode electrode, and in order to achieve an electrochemical balance, an external circuit generates a current

Methodology Applied
Scientific EffectRedox reactions: Redox Reactions

Data Source

PatentUS20240072250A1A composite anode electrode material and a preparation method thereof, an anode electrode material and a lithium ion battery
Publication Date: 2024.02.29 SVOLT ENERGY TECHNOLOGY CO LTD
  • US20240072250A1 patent drawing
  • US20240072250A1 patent drawing
  • US20240072250A1 patent drawing

AI summary

The disclosure provides a composite anode electrode material and a preparation method thereof, an anode electrode material and a lithium ion battery. The composite anode electrode material includes a defect-type transition metal oxide and a lithium titanate, wherein the lithium titanate is compounded with the defect-type transition metal oxide in the manner of coating and/or doping, the defect-type transition metal oxide is a secondary particle, and a transition metal element in the defect-type transition metal oxide is selected from any one of tungsten, yttrium and tin. The probability of a side reaction between the defect-type transition metal oxide and an electrolyte is greatly reduced and a volume expansion effect of an anode electrode of a battery in the process of deintercalating lithium ions is greatly reduced, thereby the lithium ion battery including the composite anode electrode material has a higher capacity retention rate after cycling.