Lithium Metal Transfer Laminate for Uniform Electrode Pre-Lithiation
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Solution Overview
Problem
Existing methods for pre-lithiating silicon-containing negative electrodes in lithium secondary batteries face challenges such as high initial irreversible capacity, volume change, surface side reactions, and safety risks due to the use of electrolytic plating and lithium metal transfer processes, which are difficult to control and costly.
Innovation Solution
A method involving a transfer laminate with a base material film, a transfer force enhancing layer, and a lithium metal layer, where a transfer start portion is formed by removing the lithium metal layer in a transverse direction, allowing easy transfer of the lithium metal layer onto the electrode active material layer, thereby improving surface uniformity and suppressing by-product generation.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If silicon-containing negative electrode active material is used to improve energy density, then capacity increases, but initial irreversible capacity increases and cycle life decreases
Solution Approach 1:
The patent applies preliminary action by pre-lithiating the silicon-containing negative electrode before battery assembly. This is achieved through electrochemical methods where lithium ions are introduced to the electrode in advance, compensating for the initial irreversible capacity loss. The pre-lithiation process creates a lithium reservoir that compensates for subsequent lithium consumption during initial charging cycles, thereby maintaining cycle life while preserving the high capacity benefit of silicon materials.
2Reliability
If electrochemical pre-lithiation method is used to reduce initial irreversible capacity, then cycle life improves, but production cost increases and safety risks remain
Solution Approach 1:
The patent employs parameter changes by optimizing key process parameters of the electrochemical pre-lithiation method. This includes controlling the pre-lithiation time, current density, and electrolyte composition to achieve effective pre-lithiation while minimizing resource consumption. By optimizing these parameters, the method reduces production costs and improves manufacturing efficiency while maintaining the reliability benefits of pre-lithiation.
3Quantity of substance
If lithium metal transfer process is used for pre-lithiation, then initial irreversible capacity reduces, but transfer control difficulty increases and safety risks increase
Solution Approach 1:
The patent uses an intermediary approach by employing a solid electrolyte interface (SEI) layer as a mediator during the lithium metal transfer process. This SEI layer forms a protective barrier that controls lithium ion transport, enabling smooth and controlled transfer of lithium from the lithium metal layer to the silicon-containing electrode. The intermediary SEI layer prevents direct contact between lithium metal and the electrode active material, reducing safety risks and improving transfer control while effectively reducing initial irreversible capacity.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The method enables efficient and safe pre-lithiation of the electrode active material layer, reducing initial irreversible capacity and enhancing battery performance by ensuring uniform lithium distribution and minimizing by-product generation.
Implementation Method 1
a transfer laminate comprising a base material film, a transfer force enhancing layer formed on one surface of the base material film, and a lithium metal layer formed on a surface of the transfer force enhancing layer
Implementation Method 2
lithium discharged from the positive electrode is intercalated into the negative electrode during charging, and is deintercalated from the negative electrode to return to the positive electrode again during discharging
Data Source
AI summary
A method for manufacturing an electrode for a lithium secondary battery is described, as well as an electrode intermediate, and a lithium secondary battery including the electrode. The method comprises forming an electrode current collector layer and an electrode active material layer on one surface or both surfaces of the electrode current collector layer; preparing a transfer laminate in which a base material film, a transfer force enhancing layer, and a lithium metal layer are sequentially stacked; forming a transfer start portion by removing the lithium metal layer in a transverse direction (TD); transferring the lithium metal layer having the transfer start portion formed thereon, on top of the electrode active material layer; and removing the base material film.

