Lithographic Apparatus Intermediate Layer Peeling Resistance

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Solution Overview

Problem

In lithographic apparatuses, hydrophobic coatings on sensors and other objects tend to peel off, leading to imaging errors and loss of desired properties, due to inadequate adhesion, which can result in particle generation and thermal instability.

Innovation Solution

An intermediate layer with a bond strength greater than that between the intermediate layer and the upper layer, and with Young's Modulus and Poisson ratio within 20% of the upper layer, is introduced between the upper hydrophobic layer and the substrate or lower layer to enhance adhesion and prevent peeling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a hydrophobic coating is applied to sensors and objects in lithographic apparatuses, then liquid resistance and thermal stability are improved, but adhesion deteriorates causing the coating to peel off

Engineering Contradiction:
Improveliquid resistance and thermal stabilityVSAvoidadhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

An intermediate layer is introduced between the hydrophobic coating and the substrate. This intermediate layer has a bond strength greater than that between the hydrophobic coating and the substrate, effectively mediating the adhesion issue while preserving the hydrophobic properties of the coating layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The solution employs a composite structure consisting of multiple layers: the substrate, the intermediate layer with optimized bond strength, and the hydrophobic coating layer. This composite material approach allows each layer to fulfill its specific function - the intermediate layer provides strong adhesion while the hydrophobic coating maintains liquid resistance and thermal stability.

Inventive Principle:
Principle #40Composite materials

2Strength

If a coating layer is applied to prevent peeling, then adhesion is improved, but device complexity increases

Engineering Contradiction:
ImproveadhesionVSAvoidcoating structure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The coating structure is segmented into distinct functional layers: an intermediate layer responsible for adhesion and a hydrophobic coating layer responsible for liquid resistance. This segmentation allows each layer to be optimized independently for its specific function while maintaining overall system simplicity.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentEP3559748B1A lithographic apparatus comprising an object with an upper layer having improved resistance to peeling off
Publication Date: 2023.03.29 ASML NETHERLANDS BV
  • EP3559748B1 patent drawingFigure 1
  • EP3559748B1 patent drawingFigure 2
  • EP3559748B1 patent drawingFigure 3~5

AI summary

A lithographic apparatus comprising: an object, the object comprising: a substrate and optionally a lower layer on the substrate; an upper layer; and an intermediate layer between the upper layer and the substrate, wherein a bond strength between the intermediate layer and the substrate or lower layer being greater than a bond strength between the intermediate layer and the upper layer and the intermediate layer has a Young's Modulus and/or a Poisson ratio within 20% of that of the upper layer.