Lithographic Printing Plate Overcoat Layer Scratch Resistance

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Solution Overview

Problem

Lithographic printing plate precursors face challenges with scratch resistance and developability, particularly during transport and on-press development, where the water-soluble overcoat layer can be scratched, degrading sensitivity and requiring complex development treatments.

Innovation Solution

A lithographic printing plate precursor with an overcoat layer comprising a water-soluble polymer and particles with a melting point of 70°C to 150°C, which enhances scratch resistance and developability by reducing contact area and friction, allowing for on-press development without wet treatments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a water-soluble overcoat layer is used to ensure higher sensitivity, then sensitivity is improved, but scratch resistance deteriorates

Engineering Contradiction:
ImprovesensitivityVSAvoidscratch resistance
Core Design Contradiction:
Measurement precisionVSStrength

Solution Approach 1:

The overcoat layer is formed as a composite material comprising a water-soluble polymer (providing sensitivity and water solubility) and organic resin particles (providing scratch resistance). This composite structure allows both functions to coexist: the polymer matrix ensures high sensitivity for image formation while the dispersed particles provide mechanical protection against scratches during handling and transport.

Inventive Principle:
Principle #40Composite materials

2Strength

If interleaf is inserted between precursors to prevent scratching, then scratch protection is improved, but transport complexity and time increase

Engineering Contradiction:
Improvescratch protectionVSAvoidtransport complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The overcoat layer itself provides scratch protection functionality, eliminating the need for separate protective interleaf materials. The layer serves multiple functions: ensuring sensitivity for image formation and providing mechanical protection against scratches during handling and transport, thereby simplifying the transport process and reducing complexity.

Inventive Principle:
Principle #25Self-service

3Ease of manufacture

If conventional wet development treatment is performed, then developability is improved, but environmental pollution and process complexity increase

Engineering Contradiction:
ImprovedevelopabilityVSAvoidenvironmental pollution
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The overcoat layer is designed with specific water solubility parameters that allow it to be removed under mild aqueous conditions during on-press development. This parameter optimization enables effective development without requiring complex wet treatment processes, reducing environmental pollution while maintaining good developability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The configuration provides excellent scratch resistance and developability, enabling efficient on-press development and reducing the risk of surface damage during handling and printing, while simplifying the development process.

Implementation Method 1

particles with a melting point of 70°C to 150°C, which enhances scratch resistance and developability by reducing contact area and friction

Methodology Applied
Scientific EffectFriction: Friction

Implementation Method 2

the overcoat layer includes a water-soluble polymer and particles, enabling efficient on-press development

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentEP3674096B1Lithographic printing plate precursor and lithographic printing plate fabrication method
Publication Date: 2023.03.01 FUJIFILM CORP
  • EP3674096B1 patent drawingFigure 1
  • EP3674096B1 patent drawingFigure 2
  • EP3674096B1 patent drawing

AI summary

Provided are a lithographic printing plate precursor having a support, an image recording layer, and an overcoat layer in this order, in which the overcoat layer includes a water-soluble polymer and particles, a melting point of the particles is in a range of 70°C to 150°C, and a volume average particle diameter of the particles is greater than 0.7 µm and a method of producing a lithographic printing plate obtained by using the lithographic printing plate precursor.