Lithographic Printing Plate Precursor On-Press Development

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Solution Overview

Problem

Lithographic printing plate precursors face challenges in achieving a balance between ink receptivity and printing durability, particularly during on-press development, where the incorporation of hydrophilic polymers and inorganic stratiform compounds can lead to interlayer mixing and degradation of ink receptivity.

Innovation Solution

A lithographic printing plate precursor is developed with an image-recording layer containing an infrared absorbing dye, polymerization initiator, polymerizable compound, and binder polymer with an alkylene oxide group, along with a protective layer comprising a hydrophilic polymer with specific repeating units that inhibit mixing with the image-recording layer, ensuring good ink receptivity and on-press development properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a hydrophilic polymer is incorporated into the protective layer to improve on-press development property, then the on-press development property is improved, but the polymer mixes with the image-recording layer causing degradation of ink receptivity and printing durability

Engineering Contradiction:
Improveon-press development propertyVSAvoidink receptivity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

A low molecular weight compound containing a carboxylic acid group is introduced as an intermediary substance between the hydrophilic polymer in the protective layer and the image-recording layer. This compound prevents direct contact and mixing between the polymer and image-recording layer components, thereby maintaining ink receptivity while preserving the improved on-press development property provided by the hydrophilic polymer

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The harmful mixing effect is prevented by extracting or blocking the interaction pathway between the hydrophilic polymer and the image-recording layer through the intermediary low molecular weight compound, allowing the beneficial on-press development property to be retained without the detrimental interlayer mixing

Inventive Principle:
Principle #2Taking out (Extraction)

2Duration of action of stationary object

If an inorganic stratiform compound is incorporated into the protective layer to improve printing durability, then the printing durability is improved, but it promotes interlayer mixing with the image-recording layer degrading ink receptivity

Engineering Contradiction:
Improveprinting durabilityVSAvoidink receptivity
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The low molecular weight compound containing a carboxylic acid group serves as a barrier between the inorganic stratiform compound and the image-recording layer, preventing direct interaction that would cause interlayer mixing and ink receptivity degradation, while allowing the inorganic compound to maintain its printing durability enhancement function

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If conventional development processing is used to remove unnecessary image-recording layer, then the image-forming property is achieved, but environmental pollution from waste liquid discharge occurs

Engineering Contradiction:
Improveimage-forming propertyVSAvoidenvironmental pollution
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The lithographic printing plate precursor is designed to enable on-press development where the plate itself undergoes development directly on the printing machine without requiring separate wet development processing. This self-service approach eliminates the need for conventional development tanks and waste liquid disposal systems, achieving both image-forming property and environmental protection

Inventive Principle:
Principle #25Self-service

4Device complexity

If a lithographic printing plate precursor capable of on-press development is used, then simplified plate making operation is achieved, but balance between ink receptivity and on-press development property deteriorates

Engineering Contradiction:
Improveplate making operationVSAvoidink receptivity
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The low molecular weight compound acts as a protective intermediary that allows simplified on-press development operation while preventing the chemical interaction that would otherwise degrade ink receptivity, thus maintaining both operational simplicity and printing quality

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The introduction of the low molecular weight compound changes the chemical parameters of the protective layer, creating a barrier that controls the interaction between layers and maintains the balance between ink receptivity and on-press development capability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a lithographic printing plate with enhanced ink receptivity and printing durability, maintaining ink receptivity even with specific color inks and improving on-press development performance without deterioration over time.

Implementation Method 1

contains (A) an infrared absorbing dye

Methodology Applied
Scientific EffectInfrared radiation absorption: Absorption (EM radiation)

Implementation Method 2

exposed through a mask, for example, a lith film, and then subjected to development processing

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 3

contains (B) a polymerization initiator, (C) a polymerizable compound

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentEP2492751B1Lithographic printing plate precursor and plate making method thereof
Publication Date: 2014.04.02 FUJIFILM CORP
  • EP2492751B1 patent drawing
  • EP2492751B1 patent drawing
  • EP2492751B1 patent drawing

AI summary

A lithographic printing plate precursor includes, in the following order: a support; an image-recording layer which is capable of forming an image by removing an unexposed area of the image-recording layer with at least one of printing ink and dampening water on a printing machine after exposure and contains an infrared absorbing dye, a polymerization initiator, a polymerizable compound and a binder polymer having an alkylene oxide group; and a protective layer containing a hydrophilic polymer which contains at least a repeating unit represented by the formula (1) as defined herein, a repeating unit represented by the formula (2) as defined herein, and a repeating unit represented by the formula (4) as defmed herein, and in which a content of the repeating unit represented by the formula (4) is from 0.3 to 5.0% by mole based on total repeating units of the hydrophilic polymer.