Lithium Niobate Optical Element Drift Suppression

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Solution Overview

Problem

Directly formed electrodes on lithium niobate (LN) substrates in optical modulators experience a drift phenomenon due to thermal loads, leading to instability and quality concerns, as the cause of this drift is not well understood and is difficult to control.

Innovation Solution

Using a contact metal with a standard enthalpy of formation per coordinate bond greater than niobium pentoxide, such as Co, Ni, Mo, W, or V, or an oxide conductor like indium tin oxide, to reduce oxygen deficiency and suppress the drift phenomenon in LN substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If an electrode is directly formed on an LN substrate, then integration and modulation efficiency are improved, but a drift phenomenon occurs during long-term operation

Engineering Contradiction:
Improveintegration efficiencyVSAvoidoperational stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces a contact metal layer as an intermediary between the electrode and the LN substrate. This intermediate layer prevents direct contact while maintaining electrical connection, thereby eliminating the drift phenomenon that occurs when electrodes are directly formed on the substrate, thus resolving the contradiction between integration efficiency and operational stability

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If a dielectric body (buffer layer) is interposed between LN substrate and electrode to suppress drift, then operational stability is improved, but modulation efficiency decreases

Engineering Contradiction:
Improvedrift suppressionVSAvoidmodulation efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

Instead of using a dielectric buffer layer that reduces modulation efficiency, the patent employs a conductive contact metal layer as an intermediary. This contact metal maintains electrical continuity and high modulation efficiency while preventing the drift phenomenon, thus resolving the contradiction between drift suppression and modulation efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If Ti is used as contact metal material, then ease of manufacture is improved, but drift phenomenon occurs due to oxygen deficiency

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoiddrift resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the material parameter of the contact metal from Ti to a metal with higher oxygen affinity (such as W, Mo, or V). This parameter change ensures that the contact metal does not create oxygen deficiency in the LN substrate, thereby preventing drift while maintaining ease of manufacture through similar deposition processes

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution significantly reduces the drift amount and changes due to thermal loads, maintaining high resistance and stability of the LN modulator, effectively addressing the drift issue and ensuring reliable long-term operation.

Implementation Method 1

a metal material whose standard enthalpy of formation per coordinate bond upon oxidation is greater than a standard enthalpy of formation per coordinate bond of niobium pentoxide is used

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3779574B1Optical element
Publication Date: 2024.01.17 SUMITOMO OSAKA CEMENT CO LTD
  • EP3779574B1 patent drawingFigure 1A~1B
  • EP3779574B1 patent drawingFigure 2
  • EP3779574B1 patent drawingFigure 3A~3B

AI summary

To provide an optical element in which an electrode is directly formed on an LN substrate, and a drift phenomenon is suppressed. In an optical element including: a substrate made of lithium niobate crystals; and an electrode disposed on the substrate, the substrate and the electrode are in direct contact with each other, and as a contact metal disposed on a surface of the electrode where the electrode is in contact with the substrate, a metal material whose standard enthalpy of formation per coordinate bond upon oxidation is greater than a standard enthalpy of formation per coordinate bond of niobium pentoxide is used.