LNG Ethane Extraction via Fractionation and Methane Recompression

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Solution Overview

Problem

Current methods for processing liquefied natural gas (LNG) are inefficient in separating natural gas liquids (NGL) from methane-rich gas streams, and there is a need for systems that can selectively divert LNG to vaporize both methane and ethane for enhanced processing.

Innovation Solution

The system involves passing LNG through a heat exchanger to vaporize and fractionate it, producing a methane-rich vapor stream and an NGL stream, which is then processed further to separate into liquid and gas phases, with the liquid stream being pressurized and delivered to a pipeline, and the gas stream being compressed for delivery or used as plant site fuel.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional separation methods are used to separate methane from NGL, then methane can be recovered, but the separation efficiency is insufficient and ethane cannot be selectively vaporized

Engineering Contradiction:
Improveseparation efficiencyVSAvoidselective vaporization capability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The system divides the LNG processing into distinct segments: a fractionation column separates methane-rich vapor from NGL liquid, while a parallel vaporization system selectively vaporizes ethane-plus components. This segmentation allows independent optimization of separation efficiency and selective vaporization capability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The heat exchanger serves multiple functions: it pre-heats the LNG feed, condenses the methane-rich vapor from the fractionation column, and provides heating for the selective vaporization of ethane-plus components. This multi-functionality improves overall process efficiency while addressing both separation and selective vaporization requirements.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If LNG is fully vaporized, then all components including ethane are converted to gas, but this prevents selective recovery of NGL and increases energy consumption

Engineering Contradiction:
Improveselective diversion capabilityVSAvoidenergy consumption
Core Design Contradiction:
Adaptability or versatilityVSUse of energy by moving object

Solution Approach 1:

The system incorporates dynamic control capabilities that allow selective diversion of LNG to different processing paths based on market conditions and operational requirements. The fractionation column and vaporization system can be adjusted to optimize between NGL recovery and ethane vaporization modes, enabling adaptive energy management.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system changes key operating parameters including temperature, pressure, and flow distribution to achieve selective vaporization. By controlling the temperature in the vaporization system and adjusting the diversion ratio of LNG to different paths, the system can selectively vaporize ethane-plus components while maintaining efficient methane separation, thereby reducing overall energy consumption compared to full vaporization.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If NGL recovery is maximized, then ethane and heavier hydrocarbons are recovered as liquids, but this prevents delivery of high-pressure methane-rich gas to pipeline

Engineering Contradiction:
ImproveNGL recovery quantityVSAvoidpipeline delivery pressure
Core Design Contradiction:
Quantity of substanceVSStress or pressure

Solution Approach 1:

The system introduces an intermediary vaporization system that processes the NGL-rich liquid stream. This intermediary system selectively vaporizes ethane-plus components and delivers the vaporized products to the pipeline at the required high pressure (e.g., 2000 psig), while the fractionation column continues to maximize NGL recovery. The intermediary vaporization system acts as a bridge between liquid NGL recovery and high-pressure gas delivery requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the efficiency of NGL recovery and methane-rich gas processing, allowing for selective diversion of LNG to vaporize methane and ethane, improving the overall processing efficiency and enabling cost-effective delivery of high-pressure methane-rich gas.

Implementation Method 1

LNG passes through a heat exchanger, thereby heating and vaporizing at least a portion of the LNG

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 2

The partially vaporized LNG passes to a fractionation column where a liquid stream enriched with ethane plus and a methane-rich vapor stream are withdrawn

Methodology Applied
Scientific EffectFractionation: Fractionation

Implementation Method 3

The withdrawn methane-rich vapor stream passes through the heat exchanger to condense the vapor and produce a two phase stream

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

A pump pressurizes the methane-rich liquid portion prior to vaporization and delivery to a pipeline

Methodology Applied
Scientific EffectPressurization: Pressurisation

Implementation Method 5

The methane-rich gas portion may be compressed and combined with the vaporized methane-rich liquid portion or used as plant site fuel

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentUS8156758B2Method of extracting ethane from liquefied natural gas
Publication Date: 2012.04.17 EXXONMOBIL UPSTREAM RESEARCH COMPANY(US)
  • US8156758B2 patent drawing
  • US8156758B2 patent drawing

AI summary

Methods and systems for recovery of natural gas liquids (NGL) and a pressurized methane-rich sales gas from liquefied natural gas (LNG) are disclosed. In certain embodiments, LNG passes through a heat exchanger, thereby heating and vaporizing at least a portion of the LNG. The partially vaporized LNG passes to a fractionation column where a liquid stream enriched with ethane plus and a methane-rich vapor stream are withdrawn. The withdrawn methane-rich vapor stream passes through the heat exchanger to condense the vapor and produce a two phase stream, which is separated in a separator into at least a methane-rich liquid portion and a methane-rich gas portion. A pump pressurizes the methane-rich liquid portion prior to vaporization and delivery to a pipeline. The methane-rich gas portion may be compressed and combined with the vaporized methane-rich liquid portion or used as plant site fuel.