Loadable Peptide-Free MHC Detection Molecules for Rare TCR Binding

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Solution Overview

Problem

Existing MHC-based T cell detection technologies face limitations in generating large peptide-MHC libraries, are inconsistent in detecting rare and weak interactions, and suffer from instability of pMHC complexes, leading to unreliable results, especially for cancer-associated antigens and mutation-derived neoepitopes.

Innovation Solution

The use of loadable detection molecules comprising peptide-free MHC class I molecules stabilized by a disulfide bridge, which can be loaded with antigenic peptides on demand, allowing for rapid generation of pMHC complexes and improved stability, enabling sensitive detection of rare and weak interactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional fluorescent labelled MHC multimers are used for T cell detection, then the detection can be performed, but the throughput is limited and the detection limit is high

Engineering Contradiction:
ImprovethroughputVSAvoiddetection limit
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent applies combinatorial encoding by changing the parameter of fluorophore composition. Each pMHC multimer is assigned a unique dual-color code from combinations of eight fluorophores, yielding 28 unique codes. This parameter change (from single fluorophore to combinatorial fluorophore sets) enables high-throughput detection while maintaining low detection limits through flow cytometry analysis of color combinations.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If large libraries of different peptide-MHC complexes are generated, then more epitopes can be screened, but the process becomes complex and time-consuming

Engineering Contradiction:
Improveepitope screening capacityVSAvoidlibrary generation process
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent segments the pMHC library generation process into independent components: MHC multimers are produced once and stably stored, then later combined with different fluorescently labeled peptides. This segmentation allows the complex library generation to be divided into manageable steps, reducing overall process complexity while maintaining high epitope screening capacity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary action by pre-producing and stabilizing MHC multimers with extended half-lives before they are needed for detection. These pre-prepared MHC multimers are stored and later combined with fluorescent peptides, eliminating the need to generate complete pMHC complexes from scratch for each experiment, thus reducing complexity and saving time.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If peptide exchange technologies are used to generate multiple pMHC from single MHC stock, then resource efficiency improves, but the process requires additional steps and extended duration

Engineering Contradiction:
Improveresource efficiencyVSAvoidexchange duration
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The patent performs preliminary action by pre-producing MHC multimers with extended half-lives that remain stable without requiring immediate peptide exchange. This advance preparation eliminates the need for time-consuming peptide exchange steps (UV-mediated or temperature-induced) while maintaining resource efficiency, as the stable MHC multimers can be stored and used later with different fluorescent peptides.

Inventive Principle:
Principle #10Preliminary action

4Reliability

If pMHC complexes are used for T cell detection, then antigen-specific detection is achieved, but the complexes are unstable and have limited functional lifetime

Engineering Contradiction:
Improvedetection accuracyVSAvoidpMHC functional lifetime
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent segments the pMHC complex into two independent, stable components: MHC multimers and fluorescent peptides. Each component can be produced, purified, and stored separately with extended stability. When needed, they are combined fresh to form functional pMHC complexes for detection, ensuring both reliability and extended operational duration without degradation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary action by pre-producing and stabilizing MHC multimers with extended half-lives through optimized production and storage conditions. These pre-stabilized MHC multimers maintain their structural integrity and binding capability over prolonged periods, ensuring reliable detection accuracy while extending the functional lifetime available for experiments.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides a flexible, sensitive, and fast approach for high-throughput epitope identification and TCR specificity determination, capable of detecting rare and weak interactions, and maintaining stability over prolonged periods.

Implementation Method 1

peptide-free MHC class I molecules stabilized by a disulfide bridge

Methodology Applied
Scientific EffectDisulfide bridge: Chemical Bonding

Implementation Method 2

contacting the loadable detection molecules with the at least one antigenic peptide to provide loaded detection molecules comprising at least one peptide-MHC (pMHC) class I molecule

Methodology Applied
Scientific EffectPeptide binding: Absorption (physical)

Implementation Method 3

detecting binding of the loaded detection molecules to the one or more antigenic peptide responsive T cells

Methodology Applied
Scientific EffectAntigen-antibody binding: Absorption (physical)

Data Source

PatentEP4345453B1High throughput epitope identification and t cell receptor specificity determination using loadable detection molecules
Publication Date: 2025.11.12 10X GENOMICS INC
  • EP4345453B1 patent drawingFigure 1A~1B
  • EP4345453B1 patent drawingFigure 2A~2B
  • EP4345453B1 patent drawingFigure 3A~3B

AI summary

The present invention relates to detection of interactions between antigenic peptides and binding partners, such as T cell receptors (TCR) and antigenic peptide responsive T cells. In particular, the present invention relates to the provision of loadable detection molecules with peptide-free MHC molecules utilized for high throughput epitope identification and TCR specificity determination.