Localized Excess Protons via Open-Circuit Electrolysis

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Solution Overview

Problem

Conventional acid chemicals like nitric and sulfuric acids are used in industrial processes for acid-etching and protonation of micro/nanometer materials, which are not environmentally friendly and require additional washing steps, while existing technologies fail to effectively utilize latent heat energy for generating proton motive force.

Innovation Solution

The creation of electrostatically localized excess protons at a water-substrate interface using an open-circuit water electrolysis process, forming an excess protons-substrate-hydroxyl anions capacitor-like system, which allows for acid-etching and protonation without conventional acids and harnesses latent heat energy to generate local proton motive force equivalent to Gibbs free energy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional acid chemicals (nitric and sulfuric acids) are used for acid-etching and protonation, then effective etching and protonation can be achieved, but environmental pollution increases and additional washing steps are required

Engineering Contradiction:
Improveacid-etching and protonation effectivenessVSAvoidenvironmental pollution and waste
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The invention changes the fundamental parameter of proton delivery from bulk acidic solutions to localized electrostatic fields. By applying voltage to create excess protons at specific interfaces, the system achieves etching and protonation effects without using conventional acid chemicals, thereby eliminating environmental pollution and washing steps while maintaining manufacturing precision

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the chemical mechanism (conventional acids) with an electrostatic field mechanism. Instead of using nitric or sulfuric acids to achieve etching and protonation, the system applies voltage to generate localized excess protons through electrostatic induction, substituting chemical reactions with electrostatic field effects

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Loss of energy

If latent heat energy is not utilized, then existing technologies can operate simply, but energy waste occurs

Engineering Contradiction:
Improvelatent heat energy utilizationVSAvoidsystem complexity for energy harnessing
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The invention enables the system to harness its own latent heat energy through the electrostatic field generation process. The voltage application creates not only excess protons but also utilizes the associated thermal energy, allowing the system to serve itself by converting waste heat into useful proton motive force without requiring external energy input

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention exploits the phase transition or energy state change associated with latent heat. By applying voltage to create excess protons, the system captures the thermal energy released during this electrostatic induction process and converts it into proton motive force, effectively utilizing energy that would otherwise be lost

Inventive Principle:
Principle #36Phase transitions

3Object-generated harmful factors

If electrostatically localized excess protons are created without conventional acids, then clean green chemistry processes are achieved, but new technology complexity is introduced

Engineering Contradiction:
Improvewaste reduction and environmental friendlinessVSAvoidelectrolysis system and voltage application
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The invention introduces an electrostatic field as an intermediary between the power source and the substrate. Instead of directly applying conventional acids to the material, the system uses voltage to generate excess protons at the interface, which then perform the etching and protonation functions. This intermediary approach eliminates harmful chemical waste while the voltage source and field generation provide the necessary functionality

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables clean, green chemistry processes for acid-etching and protonation without conventional acids, reduces waste, and effectively utilizes latent heat energy to drive industrial applications such as ATP synthesis, providing a sustainable and efficient solution.

Implementation Method 1

Through use of an open-circuit water electrolysis process, excess protons are created in an anode liquid chamber

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

excess protons are created in an anode liquid chamber through water electrolysis

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

the created excess protons become localized along a water-substrate or water-membrane interface

Methodology Applied
Scientific EffectElectrostatic attraction: Ion Repulsion/Attraction

Implementation Method 4

utilize latent heat energy from the environment for generation of local proton motive force

Methodology Applied
Scientific EffectThermal motion: Brownian Motion

Data Source

PatentUS10501854B2Localized excess protons and methods of making and using same
Publication Date: 2019.12.10 LEE JAMES WEIFU
  • US10501854B2 patent drawing
  • US10501854B2 patent drawing
  • US10501854B2 patent drawing

AI summary

Localized excess protons are created with an open-circuit water electrolysis process using a pair of anode and cathode electrodes for a special excess proton production and proton-utilization system to treat a substrate material plate/film by forming and using an excess protons-substrate-hydroxyl anions capacitor-like system. The technology enables protonation and/or proton-driven oxidation of plate/film and/or membrane materials in a pure water environment. The present invention represents a remarkable clean “green chemistry” technology that does not require the use of any conventional acid chemicals including nitric and sulfuric acids for the said industrial applications. The application of localized excess protons provides a special energy recycling and renewing technology function to extract latent heat including molecular thermal motion energy at ambient temperature for generating local proton motive force (equivalent to Gibbs free energy) to do useful work such as driving ATP synthesis and proton-driven oxidation of certain substrate metal atoms.