Localized Fluorescence Spectroscopy for Atomic Clock Noise Rejection

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Solution Overview

Problem

Frequency modulation spectroscopy based on fluorescence faces noise challenges due to scatter from excitation beams when the excitation wavelength is close to the fluorescence wavelength, limiting the effectiveness of spectral filtering.

Innovation Solution

An optical or magneto-optical trap is used to localize molecular entities within a narrow angle, enhancing the signal-to-noise ratio by effectively distinguishing wavelengths near the detection wavelength, and in some cases enabling fluorescence detection where none would otherwise be detectable, thereby improving the stability of atomic clocks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If spectral filtering is used to mitigate noise from excitation beam scatter, then noise is reduced, but the method becomes ineffective when excitation wavelengths are close to fluorescence wavelength

Engineering Contradiction:
Improvenoise from scatterVSAvoideffectiveness when wavelengths are close
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent transitions from spectral dimension filtering alone to adding spatial dimension by localizing the fluorescence source within an optical trap. This spatial localization creates a narrow acceptance angle for the detection system, providing an additional degree of freedom to separate signal from scatter noise even when spectral separation is insufficient.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The optical trap creates a localized region where fluorescence is generated, confining the emission to a specific spatial position and angular direction. This local quality enhancement allows the detection system to distinguish between fluorescence photons (originating from the trapped region) and scatter photons (coming from other directions), improving noise rejection when excitation and fluorescence wavelengths are close.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If an optical trap is used to localize molecular entities, then signal-to-noise ratio is improved, but device complexity increases

Engineering Contradiction:
Improvesignal-to-noise ratioVSAvoidcomplexity of trap system
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The optical trap system serves multiple functions: it localizes the fluorescence source to improve signal-to-noise ratio, confines the emission angular distribution for better spectral filtering, and provides a stable platform for repeated measurements. This multi-functionality justifies the added complexity by delivering multiple benefits from a single system component.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a higher signal-to-noise ratio for frequency modulation spectroscopy, leading to more effective oscillator regulation and a stable timekeeping in atomic clocks, even when excitation and fluorescence wavelengths are close, by localizing atoms in a small volume and using spectral filters to reject scatter while transmitting fluorescence.

Implementation Method 1

a magneto-optical trap is used to localize molecular entities within a narrow angle

Methodology Applied
Scientific EffectMagneto-optical trapping: Magneto-Optic Effects

Implementation Method 2

MOT generator 104 cools and traps atoms 110 in a MOT 112

Methodology Applied
Scientific EffectLight pressure: Radiation Pressure

Implementation Method 3

spectral filter 108, a frequency converter/modulator 114

Methodology Applied
Scientific EffectSpectral filtering: Filter (optical)

Implementation Method 4

fluorescence detector 106 configured to detect the emitted photons

Methodology Applied
Scientific EffectFluorescence detection: Fluorescence

Implementation Method 5

fluorescence detector 106

Methodology Applied
Scientific EffectPhotoelectric detection: Photoelectric Effect

Implementation Method 6

probe beam 121 derived from a 1556 nm source signal 120... excites atoms from a ground state to an excited state

Methodology Applied
Scientific EffectResonant absorption: Absorption (EM radiation)

Data Source

PatentUS11733655B2Frequency modulation spectroscopy with localized fluorescence
Publication Date: 2023.08.22 INFLEQTION QUANTUM LLC
  • US11733655B2 patent drawing
  • US11733655B2 patent drawing
  • US11733655B2 patent drawing

AI summary

A frequency-modulated spectrometry (FMS) output is used to stabilize an atomic clock by serving as an error signal to regulate the clock's oscillator frequency. Rubidium 87 atoms are localized within a hermetically sealed cell using an optical (e.g., magneto-optical) trap. The oscillator output is modulated by a sinusoidal radio frequency signal and the modulated signal is then frequency doubled to provide a modulated 788 nm probe signal. The probe signal excites the atoms, so they emit 775.8 nm fluorescence. A spectral filter is used to block 788 nm scatter from reaching a photodetector, but also blocks 775.8 nm fluorescence with an angle of incidence larger than 8° relative to a perpendicular to the spectral filter. The localized atoms lie within a conical volume defined by the 8° effective angle of incidence so an FMS output with a high signal-to-noise ratio is obtained.