LOHC Dehydrogenation Reactor Heating With Phase Change Buffer

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Dehydrogenation reactions in liquid organic hydrogen carriers are sensitive to temperature changes, requiring rapid temperature increase while maintaining stability, which existing systems struggle to achieve.

Innovation Solution

A dehydrogenation reaction apparatus utilizing a phase change material to transfer heat from a heating device to a dehydrogenation reactor, maintaining consistent temperature through latent heat transfer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If heat is applied directly to the dehydrogenation reactor to rapidly increase temperature, then the temperature increase speed is improved, but temperature stability deteriorates causing hot zones and temperature deviations

Engineering Contradiction:
Improvetemperature increase speedVSAvoidtemperature stability
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

A phase change material is introduced as an intermediary between the heating device and the dehydrogenation reactor. This material absorbs excess heat during phase transition, preventing direct thermal shocks to the reactor, and then releases the stored heat when needed, achieving both rapid temperature increase and stable temperature control without hot zones

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The heating system utilizes the phase transition properties of a phase change material (melting and freezing) to regulate heat transfer. During melting, the material absorbs heat to prevent overheating; during freezing, it releases heat to maintain temperature, enabling rapid yet stable temperature control of the dehydrogenation reactor

Inventive Principle:
Principle #36Phase transitions

2Stability of the object's composition

If the temperature of the dehydrogenation reactor is kept constant to maintain reaction stability, then temperature stability is improved, but the ability to rapidly increase temperature when needed deteriorates

Engineering Contradiction:
Improvetemperature stabilityVSAvoidtemperature increase speed
Core Design Contradiction:
Stability of the object's compositionVSSpeed

Solution Approach 1:

The phase change material is pre-positioned around the dehydrogenation reactor in a frozen state, storing potential heat energy in advance. When rapid heating is needed, the material melts and releases stored heat immediately, providing both rapid temperature increase and inherent stability through the phase transition process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system exploits the phase transition of the phase change material to dynamically balance between temperature stability and rapid heating capability. The material transitions between solid and liquid states to modulate heat flow, enabling the reactor to quickly reach target temperatures while maintaining stability during operation

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The apparatus stabilizes reactor temperature, reducing temperature deviations and preventing hot zones, thereby enhancing hydrogen conversion rates and catalyst longevity.

Implementation Method 1

a phase change material is provided between the main housing, and the dehydrogenation reactor and the heating device

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

utilizing a phase change material to transfer heat from a heating device to a dehydrogenation reactor, maintaining consistent temperature through latent heat transfer

Methodology Applied
Scientific EffectLatent heat transfer: Latent Heat

Data Source

PatentUS12496564B2Dehydrogenation reaction apparatus and system including the same
Publication Date: 2025.12.16 HYUNDAI MOTOR CO LTD
  • US12496564B2 patent drawing
  • US12496564B2 patent drawing
  • US12496564B2 patent drawing

AI summary

A dehydrogenation reaction apparatus and a system including the same are disclosed. The dehydrogenation reaction apparatus includes: a main housing; and a dehydrogenation reactor which is provided inside of the main housing and has a catalyst provided inside. In particular, the dehydrogenation reactor generates hydrogen from a liquid organic hydrogen carrier (LOHC). The dehydrogenation reaction apparatus further includes: a heating device provided inside of the main housing and configured to apply heat to the dehydrogenation reactor through a phase change material, where the phase change material is provided between the main housing, and the dehydrogenation reactor and the heating device.