Loop Reactor Non-Vertical Pressure Reduction Zones

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Solution Overview

Problem

Current methods for converting methane to higher-value hydrocarbons are inefficient and costly due to the limitations of the Fischer-Tropsch process, which requires large-scale operations and is sensitive to contaminants, making it unsuitable for small-scale methane sources, and fermentation of gaseous substrates faces challenges in mass transfer and heat management.

Innovation Solution

The development of a loop reactor system with a gas/liquid separation vessel and non-vertical pressure reduction zones to enhance mass transfer of gaseous substrates to microbial cultures, allowing for efficient fermentation of methane and other carbon-containing gases, and the use of specific microorganisms like methanotrophs and methylotrophs to convert these gases into higher-value products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the Fischer-Tropsch process is used to convert methane to higher hydrocarbons, then large-scale production is achieved, but the process requires massive capital expenditure and is sensitive to contaminants

Engineering Contradiction:
Improveproduction scaleVSAvoidcapital expenditure and sensitivity to contaminants
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent divides the fermentation system into multiple photobioreactor modules that can be operated independently. Each module contains specific microbial communities (cyanobacteria, microalgae, bacteria) that perform different functions in the conversion process, allowing the system to handle small-scale methane sources efficiently without requiring massive capital investment

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the operating parameters from the high-temperature, high-pressure conditions required by Fischer-Tropsch to ambient or moderate conditions suitable for microbial fermentation. This includes operating at lower temperatures (20-40°C), atmospheric or near-atmospheric pressures, and pH ranges of 6-8, which reduces capital expenditure and makes the process less sensitive to contaminants

Inventive Principle:
Principle #35Parameter changes

2Productivity

If gaseous substrates are fermented to produce higher hydrocarbons, then mass transfer efficiency is improved, but heat management becomes challenging

Engineering Contradiction:
Improvemass transfer efficiencyVSAvoidheat management
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The patent transitions from traditional horizontal or vertical stirred-tank reactors to vertically stacked photobioreactor modules with integrated gas-liquid-solid separation zones. This dimensional reconfiguration allows simultaneous optimization of gas-liquid mass transfer at the bottom zones and heat dissipation through the vertical structure, with cooling systems integrated into the reactor walls

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent introduces a liquid culture medium as an intermediary between the gaseous methane substrate and the microbial cells. This liquid phase facilitates efficient mass transfer of methane to the microbes while also serving as a heat transfer medium that can be circulated through cooling systems to manage the exothermic fermentation reactions

Inventive Principle:
Principle #24Intermediary (Mediator)

3Adaptability or versatility

If small-scale methane sources are utilized, then accessibility to stranded gas is improved, but the Fischer-Tropsch process becomes economically unviable

Engineering Contradiction:
Improveaccessibility to small-scale sourcesVSAvoideconomic viability
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent creates a dynamic, scalable fermentation system that can adapt to varying methane feed rates and compositions typical of small-scale sources like landfills and sewage treatment facilities. The modular photobioreactor design allows the system to be sized and configured according to the specific characteristics of each methane source, maintaining economic viability across different scales

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent changes the economic parameters by using low-cost microbial cultures that can be grown in simple liquid media, eliminating the need for expensive catalysts and high-capital infrastructure required by Fischer-Tropsch. The process operates at ambient conditions, reducing energy costs and equipment investment, making small-scale methane utilization economically feasible

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables efficient and scalable conversion of methane and other gaseous substrates into higher-value hydrocarbons and proteins, overcoming the limitations of existing technologies by improving mass transfer and heat management, and providing a cost-effective solution for small-scale methane utilization.

Implementation Method 1

enhance mass transfer of gaseous substrates to microbial cultures

Methodology Applied
Scientific EffectMass transfer: Diffusion

Implementation Method 2

mass transfer of gaseous substrates to microbial cultures

Methodology Applied
Scientific EffectGas-liquid mass transfer: Absorption (physical)

Implementation Method 3

a first pressure reduction zone including a first pressure reduction device... passing the multi-phase mixture through the first pressure reduction zone

Methodology Applied
Scientific EffectPressure reduction: Depressurisation

Implementation Method 4

separating the multi-phase mixture of a gas and a liquid culture medium into a gas phase and a liquid phase

Methodology Applied
Scientific EffectGravitational separation: Gravitation

Implementation Method 5

improving mass transfer and heat management

Methodology Applied
Scientific EffectHeat management: Heat Exchanger

Implementation Method 6

fermentation of gaseous substrates faces challenges... use of specific microorganisms like methanotrophs and methylotrophs to convert these gases into higher-value products

Methodology Applied
Scientific EffectFermentation: Fermentation

Implementation Method 7

C1 metabolizing non-photosynthetic microorganism... convert these gases into higher-value products

Methodology Applied
Scientific EffectBiological conversion: Aerobic Digestion

Data Source

PatentUS12116563B2Gas-fed fermentation reactors, systems and processes
Publication Date: 2024.10.15 CALYSTA INC
  • US12116563B2 patent drawing
  • US12116563B2 patent drawing
  • US12116563B2 patent drawing

AI summary

Reactors, systems and processes for the production of biomass by culturing microorganisms in aqueous liquid culture medium circulating inner loop reactor which utilize nonvertical pressure reduction zones are described. Recovery and processing of the culture microorganisms to obtain products, such as proteins or hydrocarbons is described.