Low-Biopersistence Inorganic Fiber Composition for 1260°C Insulation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

High-temperature refractory ceramic fibers pose health risks due to bio-persistence and inhalation hazards, and existing low bio-persistence fibers lack sufficient durability and manufacturing feasibility for high-temperature applications.

Innovation Solution

Development of inorganic fibers comprising 15-50 mol% silica, 10-35 mol% alumina, and 10-35 mol% alkali or alkaline earth metal oxides, which exhibit extended viscosity ranges for easier manufacturing, maintain mechanical integrity at high temperatures, and demonstrate low bio-persistence in acidic environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If refractory ceramic fibers are used for high-temperature insulation, then thermal insulation performance is improved, but health hazards due to bio-persistence increase

Engineering Contradiction:
Improvehigh-temperature resistanceVSAvoidhealth hazards from inhalation
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical composition parameters of the fiber by incorporating specific amounts of water-soluble salts (alkali metal oxides 5-30 wt%, alkaline earth metal oxides 5-30 wt%) into the alumino-silicate matrix. This compositional change enables the fiber to dissolve in physiological lung fluid at a controlled rate, reducing bio-persistence while preserving high-temperature stability up to 1260°C.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite fiber structure combining traditional refractory ceramic materials (alumino-silicate) with water-soluble salt components. This composite approach allows the fiber to exhibit dual characteristics: high-temperature structural integrity from the ceramic matrix and reduced bio-persistence from the soluble salt phase that dissolves in lung fluid.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If low bio-persistence fibers are developed to reduce health risks, then dissolution rate in lung fluid increases, but mechanical properties and durability at high temperatures deteriorate

Engineering Contradiction:
Improvebio-persistenceVSAvoidmechanical integrity at high temperature
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent creates localized zones of water-soluble salts within the fiber structure rather than uniform distribution. The soluble components are strategically positioned to dissolve first in physiological fluid, while the core alumino-silicate matrix maintains structural integrity at high temperatures. This local quality differentiation allows selective dissolution without compromising overall mechanical strength.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The fiber is pre-engineered with water-soluble salt components that will dissolve in advance during the biological clearance process. This preliminary dissolution action occurs before the fiber would otherwise persist in the lung, enabling macrophages to clear the dissolving fragments while the remaining structural matrix maintains mechanical properties for continued insulation service.

Inventive Principle:
Principle #10Preliminary action

3Object-affected harmful factors

If fiber composition is modified to reduce bio-persistence, then dissolution rate increases, but manufacturing complexity increases

Engineering Contradiction:
Improvebio-persistenceVSAvoidmanufacturing complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent combines multiple functional components (alumino-silicate matrix, alkali metal oxides, alkaline earth metal oxides) into a single integrated fiber manufacturing process. The water-soluble salts are incorporated during the standard fiber formation process rather than requiring separate coating or treatment steps, simplifying manufacturing while achieving the desired low bio-persistence characteristics.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The fibers provide effective thermal insulation at temperatures above 1260°C with reduced bio-persistence, preventing long-term lung retention and maintaining mechanical integrity, while being easier to manufacture and less hazardous than traditional refractory ceramic fibers.

Implementation Method 1

the fibers that are more soluble in an acidic environment may be fragmented into shorter lengths by the acidic attack within the alveolar macrophages

Methodology Applied
Scientific EffectDissolution:

Implementation Method 2

The inorganic fiber exhibits good thermal performance at use temperatures of 1260° C. and greater

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentUS12122704B2Low biopersistence inorganic fiber free of crystalline silica
Publication Date: 2024.10.22 UNIFRAX I LLC
  • US12122704B2 patent drawing
  • US12122704B2 patent drawing

AI summary

An inorganic fiber containing silica, alumina, one or more alkali metal oxides, and one or more of alkaline earth metal oxides, transition metal oxides, or lanthanide series metal oxides. The inorganic fiber exhibits good thermal performance at use temperatures of 1260° C. and greater, retains mechanical integrity after exposure to the use temperatures, is free of crystalline silica upon devitrification, is alkali flux resistant, exhibits low bio-persistence in an acidic medium, and exhibits low dissolution in a neutral medium. Also provided are thermal insulation products incorporating the inorganic fibers, a method for preparing the inorganic fiber and a method of thermally insulating articles using thermal insulation prepared from the inorganic fibers.