Low Contrast Anti-Reflection Coating for Scratch Visibility

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Solution Overview

Problem

Conventional anti-reflection coatings on transparent substrates increase the visibility of surface defects such as scratches and fingerprints due to differences in reflectance, which is a concern for applications requiring high optical transmission and surface durability.

Innovation Solution

A low-contrast anti-reflection coating with specific reflectance and thickness characteristics that reduce the visibility of surface defects by maintaining low reflectance and minimizing contrast ratios, even when surface defects occur, through the use of multiple layers with controlled refractive indices and thicknesses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional anti-reflection coatings are applied to reduce reflectance, then optical transmission is improved, but surface defect visibility increases

Engineering Contradiction:
Improveoptical transmissionVSAvoidsurface defect visibility
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by creating a gradient refractive index structure where the refractive index varies continuously from the substrate interface to the outer surface. This gradual transition minimizes reflectance at each interface while maintaining low overall reflectance, thereby reducing the contrast between pristine and defective areas. The gradient structure ensures that even when defects occur, they do not create sharp reflectance transitions that would make them highly visible.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs parameter changes by systematically varying the refractive index and thickness parameters of multiple coating layers. By optimizing these parameters, the coating achieves minimal reflectance across the visible spectrum while ensuring that defect-induced reflectance changes remain below human perception thresholds. The specific parameter ranges (refractive index 1.3-2.5, layer thickness 10-200 nm) are carefully selected to balance optical performance and defect masking.

Inventive Principle:
Principle #35Parameter changes

2Strength

If high refractive index materials are used to improve mechanical properties, then surface durability is improved, but reflectance increases

Engineering Contradiction:
Improvesurface durabilityVSAvoidreflectance
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent segments the anti-reflection coating into multiple thin layers with progressively varying refractive indices. Instead of using a single high-refractive-index material that would cause high reflectance, the coating is divided into layers with refractive indices ranging from 1.3 to 2.5. This segmentation allows the system to achieve both mechanical durability (through the presence of hard materials like SiO2, Al2O3, and Si3N4) and low reflectance (through the gradual refractive index transition).

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent utilizes composite materials by combining multiple materials with different refractive indices and mechanical properties in a single coating system. The composite structure includes materials such as SiO2, Al2O3, Si3N4, TiO2, and Ta2O5, each contributing different properties. This composite approach enables the coating to achieve both high surface durability (from hard materials) and low reflectance (from the refractive index gradient), resolving the contradiction between mechanical strength and optical performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces the visibility of surface defects by maintaining low reflectance and minimizing contrast ratios, enhancing the optical performance and durability of transparent substrates while reducing the visibility of scratches and fingerprints.

Implementation Method 1

The anti-reflection coating includes a first layer disposed on the substrate surface and a second layer disposed on the first layer, wherein the second layer has a lower refractive index than the first layer

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 2

a first layer disposed on the substrate surface and a second layer disposed on the first layer, wherein the second layer has a lower refractive index than the first layer

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS12092793B2Low contrast anti-reflection articles with reduced scratch and fingerprint visibility
Publication Date: 2024.09.17 CORNING INC
  • US12092793B2 patent drawing
  • US12092793B2 patent drawing
  • US12092793B2 patent drawing

AI summary

Embodiments of articles including a low-contrast anti-reflection coating are disclosed. The coated surface of such articles exhibits a reduced difference in reflectance between a pristine state and when a surface defect is present. In one or more embodiments, the coated surface of such articles exhibits a first average reflectance in the range from about 0.6% to about 6.0% in a pristine condition and a second average reflectance of about 8% or less after removal of a surface thickness of the anti-reflection coating. In other embodiments, the coated substrate exhibits a second average reflectance of about 10% or less, when the coated surface comprises a contaminant. In some embodiments, the coated substrate exhibits a first color coordinate (a*1, b*1) in a pristine condition and a second color coordinate (a*2, b*2) after the presence of a surface defect such that Δa*b* is about 6 or less.