Low-E Glass Protective Sheet With Low-Chloride PSA

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Solution Overview

Problem

Conventional protective sheets for Low-E glass plates fail to adequately prevent degradation and corrosion of the Low-E layers over extended periods, particularly due to chloride ions in the pressure-sensitive adhesive (PSA) layer.

Innovation Solution

A protective sheet with a PSA layer containing less than 105 μg of chloride ions per gram, formed from a water-dispersed acrylic or rubber-based PSA composition, and a substrate layer, preferably from a resin film, to minimize erosion and ensure long-term reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional PSA layer is used for protection, then adhesion and protection are achieved, but chloride ions cause degradation and corrosion of Low-E layers over time

Engineering Contradiction:
Improvelong-term protection reliabilityVSAvoidchloride ion erosion
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes chloride ions from the PSA layer through selective ion exchange resins that specifically capture chloride ions while allowing other necessary components to remain, thereby eliminating the harmful erosion effect while preserving the protective function

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameter of the PSA layer by controlling chloride ion content to 10 ppm or less, transforming the adhesive from a chloride-containing formulation to a low-chloride or chloride-free formulation that maintains adhesion without causing corrosion

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If protective sheets are used for long-term transportation and storage, then protection duration is extended, but degradation and corrosion of Low-E layers still occur

Engineering Contradiction:
Improveprotection durationVSAvoidprevention of degradation and corrosion
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-treating the PSA layer to remove chloride ions before the protective sheet is applied to the Low-E glass, ensuring that the adhesive is already free of corrosive elements before long-term contact begins, thereby preventing degradation throughout the extended protection period

Inventive Principle:
Principle #10Preliminary action

3Object-affected harmful factors

If water-dispersed PSA composition is used, then environmental friendliness is improved, but chloride ion control must be maintained

Engineering Contradiction:
Improveenvironmental impactVSAvoidchloride ion amount control
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent changes the formulation parameters of the water-dispersed PSA composition to achieve both environmental friendliness and low chloride content by selecting raw materials and processing conditions that naturally limit chloride ion generation and incorporation into the adhesive matrix

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The protective sheet effectively prevents degradation and corrosion of Low-E glass plates by limiting chloride ion exposure, maintaining adhesion and ease of removal over time, while being environmentally friendly and suitable for large glass surfaces.

Implementation Method 1

The PSA layer has a chloride ion amount of 105 μg or less per gram of PSA, determined by hot water extraction

Methodology Applied
Scientific EffectChloride ion extraction: Liquid-Liquid Extraction

Data Source

PatentUS12545815B2Protective sheet
Publication Date: 2026.02.10 NITTO DENKO CORP
  • US12545815B2 patent drawing
  • US12545815B2 patent drawing
  • US12545815B2 patent drawing

AI summary

Provided is a Low-E glass plate protective sheet having excellent long-term reliability. A Low-E glass plate protective sheet is provided. The protective sheet has a PSA layer. The PSA layer has a chloride ion amount of 105 μg or less per gram of PSA, determined by hot water extraction.