Low-E Glass Protective Sheet for Chloride-Induced Corrosion

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Solution Overview

Problem

Conventional protective sheets for Low-E glass plates fail to adequately prevent degradation and corrosion of the Low-E layers over extended periods, despite providing initial protection against physical damage and moisture ingress.

Innovation Solution

A protective sheet with a polyolefinic resin film substrate and an acrylic PSA layer containing limited chloride ions (≤8.0 µg/g) is used, which minimizes erosion and corrosion of Low-E glass plates by restricting chloride ion exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional protective sheet with PSA layer is used for Long-term protection of Low-E glass plates, then initial protection against physical damage and moisture is achieved, but chloride ions in the PSA layer cause degradation and corrosion of Low-E layers over time

Engineering Contradiction:
Improveprotection reliabilityVSAvoidchloride ion erosion
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the PSA layer by strictly limiting chloride ion content to 105 µg/g or less (preferably 50 µg/g or less, more preferably 10 µg/g or less). This parameter control prevents chloride-induced corrosion while maintaining the adhesive's protective function over long periods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a disposable protective sheet design where the substrate is made of readily available polyolefinic resin films. The sheet is intended for single-use protection during manufacturing, construction, or renovation processes, after which it is removed and discarded, avoiding long-term exposure issues.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Strength

If the PSA layer contains typical chloride ion amounts, then adhesion performance is maintained, but the Low-E layer suffers from erosion and corrosion

Engineering Contradiction:
Improveadhesive strengthVSAvoidanti-corrosion reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent modifies the PSA composition by controlling chloride ion concentration to 105 µg/g or less while maintaining effective adhesion through alternative adhesive chemistries. This parameter optimization ensures both strong bonding to the Low-E glass and prevention of corrosion.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces carefully selected adhesive formulations that act as intermediaries between the protective sheet and Low-E glass surface. These adhesives provide necessary bonding strength without introducing corrosive chloride ions, effectively mediating between structural requirements and protection requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Duration of action of moving object

If protection duration is extended for transportation and storage, then coverage period increases, but chloride ions accumulate and cause degradation

Engineering Contradiction:
Improveprotection durationVSAvoidchloride ion accumulation
Core Design Contradiction:
Duration of action of moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent extends protection duration by controlling chloride ion parameters in the PSA layer to 105 µg/g or less. This parameter control prevents cumulative corrosion effects even during extended transportation and storage periods, enabling reliable long-term protection.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies protective sheets with pre-controlled low chloride ion content before transportation and storage. This preliminary action of using low-chloride adhesives prevents future corrosion issues, ensuring the Low-E glass remains protected throughout extended periods without degradation.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The protective sheet provides long-lasting protection against degradation and corrosion of Low-E glass plates, ensuring excellent reliability and ease of removal without adhesive transfer.

Implementation Method 1

pressure-sensitive adhesive (or PSA; the same applies hereinafter) can be preferably used. In general, pressure-sensitive adhesive has characteristics of being in a soft solid (viscoelastic) state in a room temperature range and easily adhering to adherend under some pressure.

Methodology Applied
Scientific EffectPressure-sensitive adhesion: Adhesive

Implementation Method 2

pressure-sensitive adhesive has characteristics of being in a soft solid (viscoelastic) state in a room temperature range

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

the chloride ion amounts being determined by hot water extraction and ion chromatography under the conditions set forth below

Methodology Applied
Scientific EffectIon chromatography: Chromatography

Data Source

PatentEP3904088B1Protective sheet
Publication Date: 2026.01.28 NITTO DENKO CORP
  • EP3904088B1 patent drawingFigure 1
  • EP3904088B1 patent drawingFigure 2(A)~2(E)
  • EP3904088B1 patent drawing

AI summary

Provided is a Low-E glass plate protective sheet having excellent long-term reliability. A Low-E glass plate protective sheet is provided. The protective sheet has a PSA layer. The PSA layer has a chloride ion amount of 105 µg or less per gram of PSA, determined by hot water extraction.