Low-Flow Tungsten CVD for Uniform Semiconductor Deposition

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Solution Overview

Problem

High flow rates of tungsten hexafluoride in chemical vapor deposition (CVD) processes lead to poor uniformity of tungsten layers on semiconductor substrates, resulting in defects such as voids, discontinuities, and pattern loading, which reduce device yield and quality.

Innovation Solution

Implementing low-flow tungsten CVD techniques by controlling the flow rate of tungsten hexafluoride in the processing vapor to promote uniform growth, achieving similar surface uniformity to atomic layer deposition (ALD) while maintaining a faster deposition process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high flow rates of tungsten hexafluoride are used in CVD processes, then deposition speed is improved, but uniformity of tungsten layer deteriorates

Engineering Contradiction:
Improvedeposition speedVSAvoiduniformity of tungsten layer
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by optimizing the flow rate of tungsten hexafluoride to a specific range (1-10 SCCM) and controlling the ratio of tungsten hexafluoride to carrier gas (1:7200 to 10:5400). This parameter optimization resolves the contradiction by finding the optimal deposition conditions that achieve both acceptable deposition speed and high uniformity, eliminating defects while maintaining productivity.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If low flow rates of tungsten hexafluoride are used in CVD processes, then uniformity of tungsten layer is improved, but deposition speed deteriorates

Engineering Contradiction:
Improveuniformity of tungsten layerVSAvoiddeposition speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent resolves this contradiction by establishing an optimal parameter range for tungsten hexafluoride flow rate (1-10 SCCM) and carrier gas ratio (1:7200 to 10:5400). This optimized parameter set achieves uniformity comparable to ALD while maintaining significantly faster deposition speed than traditional low-flow methods, thus improving both precision and productivity simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Loss of time

If high flow rates of tungsten hexafluoride are used, then deposition process time is reduced, but defect formation increases

Engineering Contradiction:
Improvedeposition process timeVSAvoiddefect formation
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The patent applies parameter changes by controlling tungsten hexafluoride flow rate within 1-10 SCCM and maintaining specific carrier gas ratios. This optimization reduces deposition time compared to traditional low-flow methods while simultaneously eliminating defects such as voids, discontinuities, and pattern loading, thus improving both time efficiency and reliability.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If low flow rates of tungsten hexafluoride are used, then uniformity comparable to ALD is achieved, but processing throughput deteriorates

Engineering Contradiction:
Improvesurface uniformityVSAvoidprocessing throughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent resolves this contradiction by optimizing the tungsten hexafluoride flow rate to 1-10 SCCM with carrier gas ratios of 1:7200 to 10:5400. This parameter optimization achieves surface uniformity comparable to ALD while maintaining deposition speeds significantly faster than traditional low-flow CVD, thus improving both precision and throughput simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the likelihood of defect formation, increases deposition process flexibility, and enhances semiconductor device processing throughput by ensuring uniformity and selectivity of the tungsten layer deposition.

Implementation Method 1

Chemical vapor deposition includes a semiconductor process in which a solid film or layer is deposited onto a semiconductor substrate surface through a chemical reaction of a gas mixture

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

The semiconductor substrate surface may be heated and/or treated with a plasma to provide additional energy to facilitate the chemical reaction

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

The semiconductor substrate surface may be heated and/or treated with a plasma to provide additional energy to facilitate the chemical reaction

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS12252783B2Chemical vapor deposition for uniform tungsten growth
Publication Date: 2025.03.18 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12252783B2 patent drawing
  • US12252783B2 patent drawing
  • US12252783B2 patent drawing

AI summary

Low-flow tungsten chemical vapor deposition (CVD) techniques described herein provide substantially uniform deposition of tungsten on a semiconductor substrate. In some implementations, a flow of a processing vapor is provided to a CVD processing chamber such that a flow rate of tungsten hexafluoride in the processing vapor results in the tungsten layer being grown at a slower rate than a higher flow rate of the tungsten hexafluoride to promote substantially uniform growth of the tungsten layer. In this way, the low-flow tungsten CVD techniques may be used to achieve similar surface uniformity performance to an atomic layer deposition (ALD) while being a faster deposition process relative to ALD (e.g., due to the lower deposition rate and large quantity of alternating processing cycles of ALD). This reduces the likelihood of defect formation in the tungsten layer while increasing the throughput of semiconductor device processing for the semiconductor substrate (and other semiconductor substrates).