Composition including refrigerant, use thereof, refrigerator having same, and method for operating said refrigerator

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Solution Overview

Problem

Existing refrigerants like R410A have high global warming potential (GWP), necessitating the development of low-GWP alternatives for air conditioning systems.

Innovation Solution

A novel refrigerant composition comprising trans-1,2-difluoroethylene (HFO-1132(E)), 1,1-difluoroethylene (HFO-1132a), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32) is formulated within specific mass% ranges defined by a ternary composition diagram, offering a low-GWP alternative to R410A.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If refrigerant composition is optimized for low GWP, then environmental compliance is improved, but refrigeration performance may deteriorate

Engineering Contradiction:
Improveglobal warming potentialVSAvoidrefrigeration performance
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent optimizes multiple parameters simultaneously including compositional ratios, operating pressures, and temperature conditions to achieve both low GWP and high refrigeration performance. The specific formulation of HFO-1234ze(E) and HFO-1234yf in defined proportions represents this multi-parameter optimization

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs dynamic control of refrigerant flow and system operating conditions to compensate for the unique thermodynamic properties of HFO-based refrigerants, ensuring optimal refrigeration performance is maintained despite the unconventional refrigerant composition

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The refrigerant achieves a refrigerating capacity of ≥ 85% relative to R410A with a temperature glide of ≤ 5°C, maintaining effective performance while reducing GWP.

Implementation Method 1

a first heat exchanger configured to function as an evaporator in which the refrigerant flows in an evaporating manner

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a second heat exchanger configured to function as a condenser in which the refrigerant flows in a condensing manner

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

the refrigerant flows in an evaporating manner

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 4

the refrigerant flows in a condensing manner

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP3992546B1Composition including refrigerant, use thereof, refrigerator having same, and method for operating said refrigerator
Publication Date: 2026.05.06 DAIKIN INDUSTRIES LTD
  • EP3992546B1 patent drawingFigure 1
  • EP3992546B1 patent drawingFigure 2
  • EP3992546B1 patent drawingFigure 3

AI summary

Provided is a novel low-GWP mixed refrigerant. A composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), 1,1-difluoroethylene (HFO-1132a), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32).