Low-GWP Refrigerant Composition for Cold Storage

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Solution Overview

Problem

There is a lack of studies on which refrigerant with low Global Warming Potential (GWP) should be used for refrigerant cycle apparatuses for freezing or cold storage, despite the need for alternatives to high-GWP refrigerants like R410A and R404A due to global warming concerns.

Innovation Solution

A refrigerant cycle apparatus using a refrigerant composition that includes CO2, trans-1,2-difluoroethylene (HFO-1132(E)), and 2,3,3-tetrafluoro-1-propene (R1234yf), with specific mass percentage ranges defined by curves and points in a ternary composition diagram to optimize refrigerating capacity, GWP, and flammability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high-GWP refrigerants like R410A or R404A are used, then refrigerating capacity is maintained at high levels, but global warming potential increases significantly

Engineering Contradiction:
Improverefrigerating capacityVSAvoidglobal warming potential
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the refrigerant by using a specific mixture of HFO-1132(E), R32, and R1234yf with controlled mass percentages, achieving both low GWP and high refrigerating capacity through optimized compositional parameters

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite refrigerant mixture combining multiple components (HFO-1132(E), R32, R1234yf) in specific proportions to achieve properties that individual components cannot provide alone, balancing environmental compatibility with refrigerating performance

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If low-GWP refrigerants are used, then global warming potential is reduced, but refrigerating capacity decreases

Engineering Contradiction:
Improveglobal warming potentialVSAvoidrefrigerating capacity
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent optimizes the mass percentage parameters of each refrigerant component to achieve the desired balance between low GWP and high refrigerating capacity through precise compositional control

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent assigns specific functional roles to different refrigerant components based on their individual properties, with HFO-1132(E) providing low GWP characteristics and R32/R1234yf contributing to refrigerating capacity, creating local optimization within the mixture

Inventive Principle:
Principle #3Local quality

3Object-affected harmful factors

If refrigerant composition is optimized for low GWP, then environmental compatibility improves, but flammability may increase

Engineering Contradiction:
Improveenvironmental compatibilityVSAvoidflammability
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent controls the mass percentage parameters of flammable components R32 and R1234yf within specific ranges to limit flammability while maintaining low GWP characteristics through the presence of HFO-1132(E)

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses HFO-1132(E) as a non-flammable intermediary component that dilutes and stabilizes the mixture, reducing the overall flammability risk while preserving the low GWP benefits of the other components

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution achieves a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 350 or less, and lower flammability, making it suitable as a low-GWP alternative for refrigerant cycle apparatuses.

Implementation Method 1

a heat absorber... The refrigerant contains at least 1,2-difluoroethylene

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

heat absorber... refrigerant cycle apparatus for freezing or cold storage

Methodology Applied
Scientific EffectHeat absorption: Absorption (physical)

Implementation Method 3

a radiator... refrigerant cycle apparatus for freezing or cold storage

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

a compressor... refrigerant circuit includes a compressor

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 5

a decompressing portion... refrigerant circuit includes a decompressing portion

Methodology Applied
Scientific EffectExpansion: Pressure Gradient

Data Source

PatentUS20240174905A1Refrigerant cycle apparatus
Publication Date: 2024.05.30 DAIKIN INDUSTRIES LTD
  • US20240174905A1 patent drawing
  • US20240174905A1 patent drawing
  • US20240174905A1 patent drawing

AI summary

A showcase includes a refrigerant circuit and a refrigerant enclosed in the refrigerant circuit. The refrigerant circuit includes a compressor (121), a radiator (122), an expansion valve (123), and an evaporator (124). The refrigerant is a low-GWP refrigerant.