Low-Ice-Adhesion Coatings for Aerospace Surfaces

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Solution Overview

Problem

Current low-ice-adhesion coatings for aerospace applications lack durability and effectiveness in reducing ice adhesion, with previous solutions relying on sacrificial oils or greases that require frequent reapplication and offering limited long-term protection against ice growth on critical surfaces like aircraft wings and rotorblades.

Innovation Solution

Development of a low-ice-adhesion coating comprising a microstructure with a first-material phase and a second-material phase that are microphase-separated, characterized by an Anti-icing Materials International Laboratory (AMIL) Centrifuge Ice Adhesion Reduction Factor of 10 or more, utilizing a combination of hydrophobic and hygroscopic materials, including fluoropolymers and polyesters, to create a durable and long-lasting ice-repelling surface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If sacrificial oils or greases are used to reduce ice adhesion, then ice adhesion reduction is achieved, but durability and service life are limited requiring frequent reapplication

Engineering Contradiction:
Improveice adhesionVSAvoidcoating durability
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of stationary object

Solution Approach 1:

The patent employs composite materials consisting of thermoplastic elastomer base resins combined with ice-repelling agents. This composite structure integrates the adhesive properties of the thermoplastic elastomer with the ice-phobic characteristics of the additive, creating a coating that simultaneously achieves strong substrate bonding and effective ice adhesion reduction. The composite formulation eliminates the need for sacrificial oils while maintaining durable ice protection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the coating by incorporating specific ice-repelling agents into the thermoplastic elastomer matrix. This parameter change transforms the coating from a simple adhesive layer into a functional ice-protection system that maintains its ice-repelling properties throughout the coating's service life, resolving the contradiction between ice adhesion reduction and coating durability.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If thermoplastic elastomers with adhesive backings are used for durable coating, then coating durability is improved, but ice adhesion reduction benefit is not provided

Engineering Contradiction:
Improvecoating durabilityVSAvoidice adhesion
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The patent merges two previously separate functions into a single integrated coating system: the adhesive bonding function provided by thermoplastic elastomers and the ice-repelling function provided by ice-repelling agents. This combination creates a unified coating that simultaneously delivers both durable substrate attachment and effective ice adhesion reduction, eliminating the need to choose between durability and ice protection.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The thermoplastic elastomer-based coating with incorporated ice-repelling agents serves multiple functions: it provides strong adhesion to substrates like aircraft wings and rotorblades, delivers durable long-term protection, and simultaneously repels ice accumulation. This multi-functional coating system resolves the contradiction by making the coating both durable and effective at reducing ice adhesion.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Object-generated harmful factors

If deicing fluids are applied to remove ice, then existing ice contamination is removed, but no practical protection is provided in airborne icing conditions

Engineering Contradiction:
Improveice removalVSAvoidinflight protection
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent applies ice-repelling agents to substrates before exposure to icing conditions, creating a pre-established ice-phobic surface. This preliminary action ensures that when the coated aircraft encounters supercooled water droplets in flight, the ice-repelling coating actively prevents ice adhesion rather than merely removing existing ice. The protective function is established in advance, providing reliable inflight protection.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The ice-repelling coating applied to aircraft surfaces provides self-service protection during flight by automatically repelling ice accumulation without requiring active intervention. The coating continuously performs its ice-repelling function throughout the aircraft's service life, eliminating the need for repeated deicing fluid applications and providing reliable, autonomous protection against airborne icing conditions.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating significantly delays ice formation and reduces ice adhesion, maintaining its effectiveness even after abrasion, with AMIL Centrifuge Ice Adhesion Reduction Factors exceeding 10, providing enhanced durability and long-term protection against ice accumulation on aerospace surfaces.

Implementation Method 1

utilizing a combination of hydrophobic and hygroscopic materials, including fluoropolymers and polyesters

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Implementation Method 2

utilizing a combination of hydrophobic and hygroscopic materials, including fluoropolymers and polyesters

Methodology Applied
Scientific EffectHygroscopic: Absorption (physical)

Data Source

PatentUS11396607B2Compositions and methods for fabricating durable, low-ice-adhesion coatings
Publication Date: 2022.07.26 HRL LAB
  • US11396607B2 patent drawing
  • US11396607B2 patent drawing
  • US11396607B2 patent drawing

AI summary

This invention provides durable, low-ice-adhesion coatings with excellent performance in terms of ice-adhesion reduction. Some variations provide a low-ice-adhesion coating comprising a microstructure with a first-material phase and a second-material phase that are microphase-separated on an average length scale of phase inhomogeneity from 1 micron to 100 microns. Some variations provide a low-ice-adhesion material comprising a continuous matrix containing a first component; and a plurality of discrete inclusions containing a second component, wherein the inclusions are dispersed within the matrix to form a phase-separated microstructure that is inhomogeneous on an average length scale from 1 micron to 100 microns, wherein one of the first component or the second component is a low-surface-energy polymer, and the other is a hygroscopic material. The coatings are characterized by an AMIL Centrifuge Ice Adhesion Reduction Factor up to 100 or more. These coatings are useful for aerospace surfaces and other applications.