Low-k Cu Barrier Etch Stop Layer for Interconnects

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Solution Overview

Problem

Current interconnect structures in integrated circuits face challenges in reducing parasitic capacitance and leakage due to the limitations in the dielectric constant of etch stop layers, which affects etching selectivity and increases leakage in interconnect structures.

Innovation Solution

The formation of an etch stop layer using a carbon-source gas and precursors like 1-methylsilane, 2-methylsilane, and 3-methylsilane, with a high carbon content, to achieve a low dielectric constant below 4.0, reducing leakage and improving etching selectivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If the k value of etch stop layer is reduced to reduce parasitic capacitance, then parasitic capacitance is reduced, but etching selectivity is sacrificed and leakage increases

Engineering Contradiction:
Improveparasitic capacitanceVSAvoidetching selectivity and leakage
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the etch stop layer by using carbon-source gases (CH4, C2H6, C2H4) instead of traditional CO2, and by controlling the carbon content to be greater than 20 atomic percent. This parameter change enables achieving k < 4.0 while maintaining etching selectivity and reducing leakage, thereby resolving the contradiction between reducing parasitic capacitance and maintaining reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material structure by forming an etch stop layer with high carbon content embedded within the dielectric layer. This composite approach, combining carbon-rich materials with dielectric properties, achieves both low k value (reduced parasitic capacitance) and high etching selectivity with low leakage, resolving the technical contradiction

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If the k value of etch stop layer is reduced, then parasitic capacitance is reduced, but leakage increases

Engineering Contradiction:
Improveparasitic capacitanceVSAvoidleakage
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

By changing the carbon source from CO2 to hydrocarbon gases (CH4, C2H6, C2H4) and controlling carbon content > 20 atomic percent, the patent achieves a unique material composition that simultaneously reduces k value (lowering parasitic capacitance) and reduces leakage, breaking the traditional trade-off between these two parameters

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If the k value of etch stop layer is reduced, then parasitic capacitance is reduced, but etching selectivity is sacrificed

Engineering Contradiction:
Improveparasitic capacitanceVSAvoidetching selectivity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent optimizes chemical composition parameters (carbon content > 20 atomic percent, specific carbon-source gases) to create an etch stop layer that maintains high etching selectivity despite having k < .0, thereby resolving the contradiction between reducing parasitic capacitance and maintaining manufacturing precision in the etching process

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in lower leakage and improved etching rates, leading to reduced parasitic capacitance and enhanced breakdown voltage and time-dependent dielectric breakdown behavior in interconnect structures.

Implementation Method 1

an etch stop layer is formed over the metal feature and the dielectric layer using a precursor and a carbon-source gas including carbon as precursors

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Data Source

PatentUS8993435B2Low-k Cu barriers in damascene interconnect structures
Publication Date: 2015.03.31 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US8993435B2 patent drawing
  • US8993435B2 patent drawing
  • US8993435B2 patent drawing

AI summary

In the formation of an interconnect structure, a metal feature is formed in a dielectric layer. An etch stop layer (ESL) is formed over the metal feature and the dielectric layer using a precursor and a carbon-source gas including carbon as precursors. The carbon-source gas is free from carbon dioxide (CO2). The precursor is selected from the group consisting essentially of 1-methylsilane (1MS), 2-methylsilane (2MS), 3-methylsilane (3MS), 4-methylsilane (4MS), and combinations thereof.