Low Melt Toner Core-Shell Structure for Humidity Stability

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Solution Overview

Problem

Low melting toners with crystalline polyester materials exhibit reduced charging performance in high temperature and humidity conditions due to crystalline material migration to the toner surface, which interferes with charging properties.

Innovation Solution

A method of forming toner particles using an aqueous emulsion of amorphous and crystalline polymer materials, where the amorphous polymer has a higher acid number than the crystalline polymer, allowing for the aggregation and coalescence of toner particles while minimizing crystalline material migration and maintaining charging performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If crystalline polyester material is added to amorphous polyester material to achieve low melting temperature, then the melting temperature is reduced, but the charging performance deteriorates in high temperature and humidity conditions

Engineering Contradiction:
Improvemelting temperatureVSAvoidcharging performance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent applies local quality by creating a core-shell structure where the crystalline polyester is confined to the core region and the amorphous polyester forms the shell layer. This spatial differentiation ensures that the crystalline material provides low melting temperature from the core while the amorphous shell prevents surface migration, thereby maintaining charging performance even in high temperature and humidity conditions.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements the nested doll principle by placing the crystalline polyester material inside the amorphous polyester shell, creating a core-shell structure. The crystalline core is nested within the amorphous shell, which acts as a protective barrier. This nesting configuration allows the inner crystalline material to lower the overall melting temperature while the outer amorphous layer prevents the crystalline material from migrating to the surface and interfering with charging properties.

Inventive Principle:
Principle #7Nested doll (Nesting)

2Reliability

If an amorphous polyester shell is placed on the toner particle surface to cover migrated crystalline material, then charging performance may be maintained, but the manufacturing complexity increases

Engineering Contradiction:
Improvecharging performanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by forming the amorphous polyester shell during the toner particle formation process itself, rather than as a subsequent separate step. The emulsion aggregation method inherently creates the core-shell structure as the particles form, with the amorphous polyester naturally forming the outer shell. This preliminary formation of the protective shell during manufacturing avoids the need for additional post-processing steps to apply a shell coating.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the low melting temperature function and the charging performance protection function into a single integrated core-shell structure. The crystalline core and amorphous shell are formed together in one manufacturing process through emulsion aggregation, combining multiple functions (low melting point provision and surface protection) into a unified structure rather than requiring separate components or steps.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in toners with low melt temperatures and improved relative humidity sensitivity, maintaining consistent charging performance across varying humidity conditions by ensuring the crystalline material remains encapsulated, thus preventing interference with toner charging.

Implementation Method 1

forming an aqueous emulsion of the amorphous polymer material and the crystalline polymer material

Methodology Applied
Scientific EffectEmulsion: Emulsion

Implementation Method 2

the crystalline polyester material tends to migrate to the toner particle surface, where it crystallizes

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 3

aggregating toner particles from the aqueous emulsion

Methodology Applied
Scientific EffectAggregation: Coagulation

Data Source

PatentEP1936440B1Method of making a low melt toner
Publication Date: 2018.04.04 XEROX CORP

AI summary

A toner includes binder of amorphous polymer material, such as an amorphous polyester material, and a crystalline polymer material, such as a crystalline polyester material, wherein the amorphous polymer material has an acid number that is greater than an acid number of the crystalline polymer material. Further, the toner may have a minimum fusing temperature of from about 75°C to about 150°C and a relative humidity sensitivity of from about 0.5 to about 10. A method of making toner particles is also indicated.