Low-Metal Urea Fluid for SCR Catalyst Protection

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Solution Overview

Problem

Current SCR systems for diesel engines face challenges with high NOx emissions at low exhaust gas temperatures, metal contamination leading to catalyst poisoning, and the formation of undesired by-products like cyanuric acid, which reduce the efficiency and longevity of the catalyst.

Innovation Solution

A reductant fluid comprising urea, water, and a non-ionic surfactant with a metal content less than 3.8 ppm, designed to enhance atomization and reduce deposits, thereby improving NOx reduction efficiency and catalyst longevity, especially at low temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a surfactant is added to enhance atomization of urea, then droplet diameter is reduced and atomization is improved, but metal content increases due to residual metal salts from manufacturing

Engineering Contradiction:
Improveatomization qualityVSAvoidmetal contamination
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes harmful metal impurities from the surfactant through purification processes. The surfactant is subjected to treatment that selectively removes metal ions while retaining the functional surfactant molecules, thereby resolving the contradiction between needing surfactant for atomization and avoiding metal contamination that poisons the catalyst.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the purity parameter of the surfactant by implementing specific purification steps. The surfactant is purified to reduce metal content below detectable limits or to very low levels, while maintaining its surfactant properties. This parameter change allows the system to benefit from surfactant addition without suffering from metal salt contamination.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If urea is injected at low exhaust gas temperatures, then NOx reduction is maintained, but incomplete decomposition occurs forming cyanuric acid deposits

Engineering Contradiction:
ImproveNOx reduction efficiencyVSAvoidcyanuric acid deposits
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a catalyst as an intermediary substance that facilitates the decomposition of urea at lower temperatures. The catalyst provides an alternative reaction pathway with lower activation energy, enabling complete decomposition of urea to ammonia and isocyanic acid even at reduced exhaust temperatures, thereby preventing cyanuric acid formation while maintaining NOx reduction efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the temperature parameter at which urea decomposition occurs by using catalytic assistance. Instead of relying solely on high thermal energy to drive complete decomposition, the catalyst enables the reaction to proceed efficiently at lower temperatures, shifting the operational temperature window to include lower exhaust gas temperatures without forming deposits.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If metal content in reductant fluid is reduced to comply with ISO standards, then catalyst longevity is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecatalyst lifespanVSAvoidmanufacturing process complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies preliminary purification actions to the reductant fluid components during manufacturing. By implementing metal removal steps early in the production process and integrating them into the standard manufacturing workflow, the complexity is managed systematically rather than as an afterthought. This preliminary action ensures low metal content in the final product without requiring complex post-processing or quality control measures.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The reductant fluid effectively reduces NOx emissions and extends the lifespan of the SCR catalyst by minimizing metal contamination and by-product formation, even at low exhaust gas temperatures, while complying with ISO standards.

Implementation Method 1

In order to enhance atomization, a surfactant may be added. The diameter of the droplets sprayed into the exhaust gas stream should be very small

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

Evaporation of the aqueous urea composition at the exhaust gas temperature. Evaporative decomposition of urea in concurrent with evaporation of water

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

The SCR technology utilizes ammonia which is capable of reducing nitrogen oxides (NO x ) formed in the engine combustion in the presence of a catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP4122584A1Reductant fluid for the after-treatment of exhaust gas
Publication Date: 2023.01.25 BASF SE
  • EP4122584A1 patent drawingFigure 1~2
  • EP4122584A1 patent drawing
  • EP4122584A1 patent drawing

AI summary

A reductant fluid and a SCR system for the after-treatment of exhaust gas in a diesel engine is provided. The reductant fluid contains urea, water and at least one non-ionic surfactant, wherein a metal content in total of the reductant fluid is < 3.8 ppm, based on the total weight of the reductant fluid. Further, the invention relates to the use of said reductant fluid for after-treatment of an exhaust gas of a diesel engine in a SCR system, wherein the exhaust gas contains nitrogen oxides (NOx) as well as to reduce the content of nitrogen oxides (NOx) in the exhaust gas of a diesel engine in a SCR system.