Low-Odor Polyolefin Resin Foam Through Aldehyde Content Control

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Solution Overview

Problem

Conventional methods fail to adequately suppress odor emission from polyolefin resin foams, particularly in hot weather conditions, due to the presence of aldehyde compounds with 6 to 11 carbon atoms.

Innovation Solution

A polyolefin resin foam with controlled aldehyde content of 0.1 ppm or less is produced by adjusting the amounts of antioxidants and crosslinking aids in the foamable composition, followed by ionizing radiation and controlled foaming conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional polyolefin resin foam is used, then heat resistance and heat insulation are excellent, but odor emission occurs especially in hot weather

Engineering Contradiction:
Improveodor emissionVSAvoidheat resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters by introducing specific antioxidants (1.0-5.0 parts by mass relative to 100 parts by mass of polyolefin resin) and crosslinking aids (2.0-5.0 parts by mass relative to 100 parts by mass of polyolefin resin), then applies ionizing radiation (1.0-5.0 Mrad) to transform the resin structure. This reduces aldehyde compounds to 0.1 ppm or less while maintaining the foam's heat resistance and insulation properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the harmful thermal degradation process that produces odorous aldehyde compounds into a beneficial crosslinking process. By controlling the crosslinking conditions and using specific additives, the thermal energy that would normally cause decomposition is instead used to create a crosslinked structure that suppresses further degradation and odor generation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Strength

If crosslinking is applied to improve bonding and rigidity, then heat resistance and molding properties improve, but manufacturing complexity increases

Engineering Contradiction:
ImproverigidityVSAvoidmanufacturing process
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention replaces complex mechanical crosslinking processes with ionizing radiation (electron beams or gamma rays). This substitution eliminates the need for additional crosslinking equipment, molds, and processing steps while achieving uniform crosslinking throughout the foam structure, thereby improving rigidity without increasing manufacturing complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The crosslinking aid is incorporated into the foam composition during the initial mixing stage, before foaming and crosslinking. This preliminary incorporation ensures uniform distribution of the crosslinking catalyst throughout the resin matrix, enabling efficient and uniform crosslinking when ionizing radiation is applied, thereby simplifying the overall manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly reduces odor emission by limiting aldehyde compounds, ensuring minimal odor even in hot weather, while maintaining mechanical strength and flexibility.

Implementation Method 1

irradiating the foamable sheet with ionizing radiation in an irradiation dose of 1.2 to 2.5 Mrad to produce a crosslinked foamable sheet

Methodology Applied
Scientific EffectIonizing radiation: Radiation

Implementation Method 2

a composition containing a polyolefin resin and a foaming agent is foamed by heating

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentEP3778739B1Polyolefin resin foam, method for producing polyolefin resin foam, and molded body
Publication Date: 2025.09.03 SEKISUI CHEMICAL CO LTD

AI summary

The present invention is a polyolefin resin foam having a content of aldehyde compounds having 6 to 11 carbon atoms of 0.1 ppm or less. The present invention can provide a polyolefin resin foam capable of reducing odor emission.