Two-Stage Gasification for Low Rank Fuel Pyrolysis

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Solution Overview

Problem

Low rank fuels, characterized by low heating value and high oxygen content, are inefficiently processed in traditional gasification systems due to their watery slurry formation, making them unsuitable for effective syngas production.

Innovation Solution

A gasification system that includes a first gasifier for pyrolysis to produce hydrocarbons and fixed carbon, a second gasifier for syngas production using the fixed carbon, and a recycling conduit to mix recycled syngas with hydrocarbons, enhancing heating and efficiency, integrated with a combined-cycle power generation plant and cooler for energy recovery.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional gasification systems are used with low rank fuels, then syngas production is attempted, but the process becomes inefficient due to watery slurry formation and low heating value

Engineering Contradiction:
Improvesyngas production efficiencyVSAvoidprocess suitability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The gasification process is divided into two separate gasifiers: a first gasifier for pyrolysis to produce hydrocarbons and fixed carbon, and a second gasifier for syngas production using the fixed carbon. This segmentation allows each unit to be optimized for its specific function, resolving the inefficiency of trying to process low rank fuels directly in traditional syngas gasifiers.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Fixed carbon acts as an intermediary substance between the low rank fuel and the syngas production process. The first gasifier converts low rank fuel into fixed carbon and hydrocarbons, which then serves as suitable feedstock for the second gasifier to produce efficient syngas, bridging the gap between unsuitable low rank fuel and syngas production requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Use of energy by moving object

If low rank fuels are gasified directly, then syngas is produced, but energy efficiency deteriorates due to low heating value and high moisture content

Engineering Contradiction:
Improveenergy efficiencyVSAvoidmoisture content
Core Design Contradiction:
Use of energy by moving objectVSQuantity of substance

Solution Approach 1:

The first gasifier performs preliminary pyrolysis to remove moisture and volatiles from the low rank fuel before the material enters the second gasifier for syngas production. This preliminary action concentrates the carbon content and removes water, thereby improving the energy efficiency of the subsequent syngas generation process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system changes the physical and chemical parameters of the fuel through pyrolysis in the first gasifier, transforming low rank fuel with high moisture and low heating value into fixed carbon with concentrated energy content, making it suitable for efficient syngas production in the second gasifier.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If low rank fuels are processed in conventional systems, then gasification occurs, but heating efficiency is insufficient due to low heating value

Engineering Contradiction:
Improveheating efficiencyVSAvoidheating value
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

The system merges the pyrolysis process and gasification process into an integrated two-stage system where the first gasifier produces hydrocarbons and fixed carbon through pyrolysis, and the second gasifier produces syngas. This combination allows the system to overcome the low heating value limitation by concentrating carbon in the fixed carbon before gasification.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The pyrolysis process in the first gasifier changes the thermal and chemical parameters of the low rank fuel, converting it into fixed carbon with higher carbon concentration and improved heating characteristics, enabling more effective heating and gasification in the second stage.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If low rank fuels are gasified, then syngas is produced, but fuel utilization is poor due to high oxygen content and low heating value

Engineering Contradiction:
Improvefuel utilizationVSAvoidoxygen content
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The first gasifier extracts and removes oxygen and volatile components from the low rank fuel through pyrolysis, leaving behind concentrated fixed carbon. This extraction process eliminates the harmful effects of high oxygen content and low heating value, allowing the second gasifier to efficiently convert the purified fixed carbon into syngas.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Pyrolysis in the first gasifier fundamentally changes the compositional parameters of the fuel by removing oxygen and volatiles, transforming low rank fuel into fixed carbon with improved fuel characteristics that are highly suitable for efficient gasification and syngas production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system efficiently converts low rank fuels into hydrocarbon-rich syngas, improving energy production and utilization of low cost, abundant fuels like low rank coal, while reducing moisture and volatile content, thereby enhancing power generation and chemical production capabilities.

Implementation Method 1

a first gasifier configured to receive low rank fuel, the first gasifier further configured to gasify the low rank fuel to produce hydrocarbons and fixed carbon

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

a cooler configured to cool the syngas stream

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 3

The recycled syngas stream is mixed with the hydrocarbons to produce a hydrocarbon-rich syngas stream

Methodology Applied
Scientific EffectConvection: Convection

Data Source

PatentUS9453171B2Integrated steam gasification and entrained flow gasification systems and methods for low rank fuels
Publication Date: 2016.09.27 AIR PROD & CHEM INC
  • US9453171B2 patent drawing
  • US9453171B2 patent drawing
  • US9453171B2 patent drawing

AI summary

In one aspect, a gasification system for use with low rank fuel is provided. The system includes a first gasifier positioned to receive a feed of low rank fuel, the first gasifier being configured to gasify the low rank fuel to produce hydrocarbons and fixed carbon. The system also includes a second gasifier configured to produce a syngas stream using the received fixed carbon, a cooler configured to receive and cool the syngas stream, and a first conduit coupled between the cooler and the first gasifier. The first conduit is configured to recycle at least a portion of the syngas stream to the first gasifier to facilitate heating low rank fuel within the first gasifier. The recycled syngas stream is mixed with the hydrocarbons to produce a hydrocarbon-rich syngas stream. The system also includes a second conduit coupled to the first gasifier for receiving the hydrocarbon-rich syngas stream.