Low-Refractive-Index Organic Compounds for EL Light Extraction

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Solution Overview

Problem

Existing organic light-emitting devices face challenges with low outcoupling efficiency due to reflection caused by differences in refractive indices between layers, which adversely affect carrier-transport properties and reliability, making it difficult to form low refractive index layers without compromising other critical characteristics.

Innovation Solution

Development of an organic compound with a low refractive index and carrier-transport property, specifically represented by general formulas (G1) to (G6), which can be used in the EL layer to enhance hole-transport capabilities and improve emission efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a layer with low refractive index is formed in the EL layer to reduce reflection and improve outcoupling efficiency, then external quantum efficiency is improved, but carrier-transport property and reliability deteriorate

Engineering Contradiction:
Improveoutcoupling efficiencyVSAvoidcarrier-transport property
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the organic compound by introducing specific substituents (cyclohexyl groups at positions 2 and 6 of the phenyl ring) to achieve a low refractive index while maintaining adequate carrier-transport properties. This structural parameter modification allows the material to simultaneously satisfy optical and electrical requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining specific organic compound structures (formula G1-G6) that integrate both optical properties (low refractive index) and electrical properties (carrier-transport capability) into a single material system, rather than treating these as separate functional layers.

Inventive Principle:
Principle #40Composite materials

2Reliability

If organic compounds with many unsaturated bonds are used to improve carrier-transport property, then carrier-transport property is improved, but refractive index increases

Engineering Contradiction:
Improvecarrier-transport propertyVSAvoidrefractive index
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent modifies the chemical structure by controlling the degree of saturation in specific positions of the molecular structure. The cyclohexyl groups (saturated) are introduced to reduce overall refractive index while the aromatic rings (unsaturated) are retained to maintain carrier-transport pathways, achieving a balanced parameter optimization.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound with a low refractive index and hole-transport property enhances the external quantum efficiency of light-emitting devices, reducing power consumption and improving reliability.

Implementation Method 1

Light-emitting devices (organic EL devices) that use organic compounds and utilize electroluminescence (EL) have been put into practical use. Carriers are injected by application of voltage to this device, and recombination energy of the carriers is used, whereby light emission can be obtained from the light-emitting material.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12460130B2Organic compound, light-emitting device, light-emitting apparatus, electronic equipment, lighting device, and electronic device
Publication Date: 2025.11.04 SEMICON ENERGY LAB CO LTD
  • US12460130B2 patent drawing
  • US12460130B2 patent drawing
  • US12460130B2 patent drawing

AI summary

A novel organic compound is provided. A novel organic compound having a carrier-transport property is provided. A novel organic compound having a hole-transport property is provided. An organic compound having a low refractive index is provided. An organic compound having a low refractive index and a carrier-transport property is provided. An organic compound having a low refractive index and a hole-transport property is provided. An organic compound represented by the following general formula (G1) is provided.