Low Specific Gravity Heat-Shrinkable Label Film

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Solution Overview

Problem

Heat-shrinkable label films used on containers face challenges such as environmental contamination from PVC, excessive shrinkage issues with PET, and poor printability with PS, while also complicating recycling due to adhesion and material incompatibility, necessitating a film that is easily removable and has a low specific gravity to float on water for efficient collection.

Innovation Solution

A three-layered heat-shrinkable label film is developed with a foamed polystyrene intermediate layer and non-foamed PET layers on either side, achieved through coextrusion and drawing, which provides a low specific gravity of less than 1, allowing the film to float on water and maintain necessary properties like heat resistance and printability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If PVC film is used as heat-shrinkable label film, then heat resistance, printability, gloss, transparency, and adhesiveness are improved, but environmental contamination increases due to endocrine-disrupting chemicals

Engineering Contradiction:
Improveheat resistanceVSAvoidenvironmental contamination
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite structure consisting of a PS-based film layer and a PET-based film layer. The PS layer provides printability and low specific gravity, while the PET layer provides heat resistance and structural stability. This composite approach allows the label film to meet performance requirements without using harmful PVC materials.

Inventive Principle:
Principle #40Composite materials

2Reliability

If PET film is used as label film, then heat resistance is improved, but specific gravity increases to about 1.35, increasing production cost

Engineering Contradiction:
Improveheat resistanceVSAvoidspecific gravity
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent applies local quality by creating a multi-layer structure where each layer has specific properties optimized for its function. The PS layer (lower specific gravity) is positioned where printability and buoyancy are needed, while the PET layer (higher specific gravity but excellent heat resistance) is positioned to provide thermal stability. This localized optimization achieves overall heat resistance without the full weight penalty of pure PET.

Inventive Principle:
Principle #3Local quality

3Reliability

If PET film is used as label film, then heat resistance is improved, but excessive shrinkage occurs during thermal shrinkage, causing dents or deformation on synthetic resin containers

Engineering Contradiction:
Improveheat resistanceVSAvoidshrinkage control
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent utilizes parameter changes by controlling the glass transition temperatures and shrinkage characteristics of each layer. The PS layer has a lower glass transition temperature and different shrinkage behavior compared to the PET layer. During heat shrinkage, these parameter differences allow the layers to work together - the PET layer provides heat resistance while the PS layer's shrinkage characteristics help control overall dimensional changes, preventing excessive shrinkage and container deformation.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If PS film is used for printing, then eco-friendliness is improved by using alcohol-based solvent, but printability deteriorates

Engineering Contradiction:
Improveeco-friendlinessVSAvoidprintability
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent uses the PS-based film layer as an intermediary that is specifically optimized for printing. The PS material serves as a mediator between the printing process and the final label appearance, providing a surface that accepts alcohol-based solvent inks well. The layered structure allows the PS layer to handle the printing function while the PET layer handles the heat resistance function, resolving the conflict between eco-friendly printing and performance requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

5Reliability

If label film has high adhesion to container, then label stability is improved, but recycling difficulty increases due to separation complexity

Engineering Contradiction:
Improvelabel stabilityVSAvoidrecycling ease
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies segmentation by creating a multi-layer label film structure with distinct PS and PET layers that have different physical and chemical properties. This segmentation enables selective separation during recycling - the layers can be differentiated and separated more easily than a homogeneous material, facilitating recycling processes while maintaining adequate adhesion during use through the combined properties of the layered structure.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The film effectively floats on water, simplifying recycling, reduces production costs, and meets requirements for heat resistance, printability, and appearance, while being easily removable from containers, thus addressing environmental and recycling concerns.

Implementation Method 1

a foamed intermediate layer (10) comprising polystyrene as a principal component... providing a low specific gravity of less than 1, allowing the film to float on water

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Implementation Method 2

Hot air is externally applied to the heat-shrinkable label film on the container, as a result of which the heat-shrinkable label film is shrunk and adhered closely to the outer circumference of the container

Methodology Applied
Scientific EffectThermal contraction: Thermal Contraction

Data Source

PatentUS9944054B2Heat-shrinkable film for label with low specific gravity and method for preparing the same
Publication Date: 2018.04.17 DONGIL CHEM CO LTD
  • US9944054B2 patent drawing
  • US9944054B2 patent drawing
  • US9944054B2 patent drawing

AI summary

A heat-shrinkable label film includes a foamed layer having polystyrene as a principal component, and a pair of non-foamed layers adhesively melted to either side of the foamed layer, wherein the foamed layer and the pair of the non-foamed layers are coextruded to provide a low specific gravity less than 1.0. The film is prepared by coextruding to form the several layers completing a non-drawn film; and drawing the non-drawn film in a transverse direction (TD) at a drawing ratio of 3.5 to 5.5. The foamed ratio of the foamed layer is in the range of 5 to 20%. The thickness of the foamed layer is 60 to 90% of the total thickness of the film; and the thickness of each non-foamed layer is 5 to 20% of the total thickness of the film. The heat-shrinkable label film has a thickness of 30 to 60 μm.