Low-Temperature Refrigerant Blend With Lower GWP and Oil Compatibility

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Solution Overview

Problem

Current refrigerants like R404A and R507 have high Global Warming Potential (GWP) and are ozone-depleting, requiring replacement in refrigeration systems without significant changes to lubricants or hardware, while also needing to be non-flammable and energy-efficient.

Innovation Solution

A refrigerant composition comprising HFCs such as HFC 134a, HFC 125, HFC 32, HFC 227ea, and HFC 152a, with optional hydrocarbon components, which reduces GWP to below 2000 and ensures non-flammability under all conditions, allowing the use of hydrocarbon oils and compatibility with existing systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If HFC compositions R404A and R507 are used as replacements for ODS, then energy efficiency and non-flammability are improved, but Global Warming Potential increases to the high end of the range

Engineering Contradiction:
Improveenergy efficiencyVSAvoidGlobal Warming Potential
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by introducing a specific blend of HFCs (R134a, R125, R32, R227ea, R152a) with controlled percentages to achieve a new refrigerant composition that maintains desirable thermodynamic properties while reducing GWP below 2000

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite refrigerant mixture combining multiple HFC components in specific ratios, where each component contributes different properties: R134a and R125 provide stability and low GWP, R32 enhances refrigerating effect, R227ea and R152a improve lubricant compatibility and oil return

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If R404A and R507 are replaced with lower GWP alternatives, then environmental impact is reduced, but compatibility with existing lubricants and hardware becomes problematic

Engineering Contradiction:
ImproveGlobal Warming PotentialVSAvoidlubricant compatibility
Core Design Contradiction:
Object-generated harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent adjusts the compositional parameters to include R227ea (2-12%) and R152a (2-10%) which have specific solubility characteristics that enable compatibility with both hydrocarbon and synthetic lubricants, allowing retrofitting of existing systems

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses R227ea and R152a as intermediary components that mediate between the refrigerant and lubricant, improving solubility and preventing oil return problems that occur with traditional low-GWP alternatives

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-generated harmful factors

If hydrocarbon components are added to reduce GWP further, then environmental performance improves, but flammability risk increases

Engineering Contradiction:
ImproveGlobal Warming PotentialVSAvoidflammability
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The patent precisely controls the percentage of flammable components (R32 at 25-45%, R152a at 2-10%) and combines them with non-flammable HFCs (R134a, R125, R227ea) in ratios that maintain the blend below flammability thresholds while achieving GWP reduction

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite mixture where flammable and non-flammable components are combined in specific proportions, leveraging the properties of each: R32 and R152a provide refrigerating effect and lubricant compatibility, while R134a, R125, and R227ea provide stability and fire suppression

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS9023231B2Non ozone depleting and low global warming potential refrigerants for low temperature refrigeration
Publication Date: 2015.05.05 RPL HLDG LTD

AI summary

Non ozone depleting and non flammable refrigerant compositions with GWPs less than 2,000 ITH which replace R404A, R507, HCFC22 and CFC502 in refrigeration systems.