Low-Temperature Cross-Section Repair Material for Concrete

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Solution Overview

Problem

Current cross-section repair materials for concrete structures face challenges in curing at extremely low temperatures, such as -25°C, leading to prolonged curing times and insufficient compressive strength, while also posing safety concerns with the use of ultraviolet light curing and inadequate workability.

Innovation Solution

A low-temperature-curable cross-section repair material comprising a radical polymerizable resin composition, cobalt metal salt, hydroxyl group-containing aromatic tertiary amine, organic peroxide, and inorganic filler, which includes specific components like vinyl ester resin, urethane (meth)acrylate resin, and polyester (meth)acrylate resin, along with radical polymerizable unsaturated monomers, to facilitate rapid curing and enhanced strength development at low temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional concrete repair materials are used at extremely low temperatures, then the material can be applied, but the curing time becomes excessively long and compressive strength is insufficient

Engineering Contradiction:
Improvecuring temperatureVSAvoidcuring time
Core Design Contradiction:
TemperatureVSLoss of time

Solution Approach 1:

The patent changes the chemical composition parameters of the repair material by incorporating specific low-temperature-curable resins (epoxy resin, polyester resin, or vinyl ester resin) and reactive diluents with low freezing points. This compositional parameter change enables the material to maintain workability and achieve proper curing at extremely low temperatures down to -25°C, directly resolving the contradiction between low curing temperature and excessive curing time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite repair material system combining multiple components: base resin (epoxy/polyester/vinyl ester), reactive diluent, curing agent, and filler. This composite formulation synergistically enables low-temperature curing while maintaining adequate compressive strength and reducing curing time, addressing both the temperature and time constraints simultaneously

Inventive Principle:
Principle #40Composite materials

2Temperature

If resin-based cross-section repair material is used to enable low-temperature curing, then curing at -25°C becomes possible, but work safety deteriorates due to the need for ultraviolet light curing

Engineering Contradiction:
Improvecuring temperatureVSAvoidwork safety
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent replaces the ultraviolet light curing mechanism with a chemical curing mechanism using reactive diluents and curing agents that can polymerize at low temperatures without requiring UV radiation. This substitution eliminates the safety hazards associated with UV exposure while maintaining the ability to cure at -25°C, resolving the contradiction between low-temperature capability and work safety

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Temperature

If floor resins in refrigerated warehouses are used to achieve low-temperature curing, then curing at extremely low temperatures is possible, but compressive strength characteristics become insufficient

Engineering Contradiction:
Improvecuring temperatureVSAvoidcompressive strength
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent formulates a composite repair material combining specific base resins (epoxy/polyester/vinyl ester) with reactive diluents, curing agents, and fillers in optimized proportions. This composite structure provides both low-temperature curability and adequate compressive strength for concrete repair applications, distinguishing it from ordinary floor resins that lack the necessary strength characteristics

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent adjusts the chemical composition parameters including resin type, diluent ratio, curing agent selection, and filler content to optimize both low-temperature curing performance and compressive strength. These parameter changes ensure the material meets the specific requirements for concrete cross-section repair at extremely low temperatures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material allows for rapid curing and excellent strength development at -25°C, improving workability and compressive strength, while ensuring safety and efficiency in concrete repair processes.

Implementation Method 1

a radical polymerizable resin composition (A), a cobalt metal salt (B), a hydroxyl group-containing aromatic tertiary amine (C-1)... an organic peroxide (D)... wherein the radical polymerizable resin composition (A) contains at least one radical polymerizable resin (A-1)

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Implementation Method 2

a cobalt metal salt (B), a hydroxyl group-containing aromatic tertiary amine (C-1)... an organic peroxide (D)... wherein the radical polymerizable resin composition (A) contains at least one radical polymerizable resin (A-1)

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP3260479B1Use of a low-temperature-curable cross-section repair material, and cross-section repair method using same
Publication Date: 2019.11.27 RESONAC HOLDINGS CORP
  • EP3260479B1 patent drawing
  • EP3260479B1 patent drawing
  • EP3260479B1 patent drawing

AI summary

Provided is a low-temperature-curable cross-section repair material which can be cured in a short period of time, even in extremely low temperature environments of -25°C, and which exhibits excellent workability and strength development. Also provided is a cross-section repairing method using the same. The low-temperature-curable cross-section repair material is characterized by: comprising 100 parts by of a radical polymerizable resin composition (A), 0.1-10 parts by of a hydroxyl group-containing aromatic tertiary amine (C-1), 0.1-10 parts by of an organic peroxide (D), and 1.0-500 parts by of an inorganic filler (E); and the radical polymerizable resin composition (A) comprising at least one type of radical polymerizable resin (A-1) selected from the group consisting of vinyl ester resins, urethane (meth)acrylate resins and polyester (meth)acrylate resins, and a radical polymerizable unsaturated monomer (A-2) having at least two or more (meth)acryloyl groups per molecule thereof.