Low-Temperature Surfactant Blend for Enhanced Oil Recovery

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Solution Overview

Problem

Current enhanced oil recovery methods face challenges due to the low stability of anionic surfactants at low temperatures, leading to viscosity and gelling issues that affect the efficiency of subterranean petroleum recovery.

Innovation Solution

Aqueous solutions comprising nonionic surfactants with specific structures, di-sulfonated anionic surfactants, and alcohols are injected into subterranean formations to enhance oil recovery, maintaining stability at temperatures as low as -5°C, thereby preventing phase separation and viscosity problems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If anionic surfactants are used as wettability modifiers in enhanced oil recovery, then oil recovery efficiency is improved, but stability at low temperatures deteriorates leading to viscosity and gelling problems

Engineering Contradiction:
Improveoil recovery efficiencyVSAvoidstability at low temperatures
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent combines anionic surfactants with nonionic surfactants and alcohols to form a composite aqueous composition. This composite approach leverages the synergistic effects where nonionic surfactants and alcohols stabilize the anionic surfactant system at low temperatures, preventing phase separation and viscosity issues while maintaining effective wettability modification for oil recovery.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters by incorporating specific nonionic surfactants and alcohols in optimized ratios. This parameter change transforms the system from an unstable single-surfactant solution to a stable multi-component system that maintains flowability and pumpability at low temperatures while retaining oil recovery effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If aqueous anionic surfactant solutions are used at low temperatures, then wettability modification is achieved, but phase separation occurs resulting in high viscosity and gelling

Engineering Contradiction:
Improvewettability modification effectivenessVSAvoidphase separation and high viscosity
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces nonionic surfactants and alcohols as intermediary substances that mediate between the anionic surfactant and the aqueous environment at low temperatures. These intermediaries prevent direct phase separation by forming stable micellar structures that maintain system homogeneity and prevent gelling, while allowing the anionic surfactant to perform its wettability modification function.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If conventional surfactant blends are used for enhanced oil recovery, then oil displacement is improved, but transportation and storage become problematic due to viscosity and gelling at low temperatures

Engineering Contradiction:
Improveoil displacement efficiencyVSAvoidtransportation and storage
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent optimizes the compositional parameters by incorporating specific ratios of nonionic surfactants and alcohols that lower the pour point and maintain fluidity at low temperatures. This parameter optimization ensures the composition remains pumpable and transportable during winter conditions while maintaining effective concentrations for oil displacement in the reservoir.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution ensures the stability and effectiveness of the aqueous wettability compositions at low temperatures, improving the efficiency of oil recovery by maintaining flowability and pumpability, thus enhancing the recovery factor.

Implementation Method 1

The wettability of a rock can be naturally modified by adsorption of polar compounds

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

It is known that the solubility of nonionic surfactants in water decreases with temperature and that a nonionic surfactant eventually becomes insoluble when reaching what is known as a cloud point temperature

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 3

Wettability modifiers are defined as a surfactants capable of changing the affinity of reservoir rock in favorable manner

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Data Source

PatentUS11584881B2Low-temperature stabilized surfactant blend for enhanced oil recovery
Publication Date: 2023.02.21 DOW GLOBAL TECHNOLOGIES LLC
  • US11584881B2 patent drawing
  • US11584881B2 patent drawing
  • US11584881B2 patent drawing

AI summary

Disclosed is a temperature stabilized aqueous wettability composition and method of use for the recovery of petroleum from subterranean formulations. Said aqueous wettability composition comprises a polyethylene oxide nonionic surfactant, a disulfonated anionic surfactant, and one or more alcohol.