Low-Temperature Phosphorus-Free Ware Wash Detergent Against Scale

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Solution Overview

Problem

Existing ware wash detergents, particularly those used in institutional and commercial settings with hard water, face challenges with scale build-up due to high alkalinity and elevated temperatures, leading to aesthetic issues and energy inefficiencies, and there is a need for phosphorus-free alternatives that effectively reduce scale formation without using phosphates or nitrilotriacetic acid (NTA) due to ecological concerns.

Innovation Solution

Phosphorus-free detergent compositions comprising aminocarboxylates, water conditioning polymers, and alkalinity sources, which operate at low temperatures (120°F to 140°F) to prevent scale build-up on treated surfaces, eliminating the need for surfactants and phosphorus-containing builders.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high alkalinity and elevated temperatures are used in ware wash detergents, then cleaning efficacy is improved, but scale build-up increases

Engineering Contradiction:
Improvecleaning efficacyVSAvoidscale build-up
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention removes phosphates and phosphorus-containing compounds from the detergent formulation, extracting the harmful element that causes ecological damage while replacing it with alternative water conditioning polymers that provide scale prevention without the harmful effects

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical parameters of the detergent by substituting phosphate-based sequestrants with alternative polymers such as polyacrylates and polycarboxylates, which provide similar water conditioning benefits without contributing to ecological harm

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If phosphates are used as sequestrants in detergent compositions, then scale build-up is reduced, but ecological harm increases

Engineering Contradiction:
Improvescale build-upVSAvoidecological harm
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The invention extracts phosphates and phosphorus-containing compounds from the detergent formulation, removing the source of ecological harm while maintaining scale prevention functionality through alternative polymers

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses biodegradable alternative polymers that break down more readily in the environment compared to persistent phosphates, providing a temporary but effective scale prevention solution that does not accumulate in ecosystems

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-generated harmful factors

If NTA-containing aminocarboxylate components are used as sequestrants, then scale build-up is controlled, but carcinogenic risk increases

Engineering Contradiction:
Improvescale build-upVSAvoidcarcinogenic risk
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The invention removes NTA-containing aminocarboxylate components from the formulation, extracting the carcinogenic element while replacing it with alternative polymers that provide scale control without health risks

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention employs biodegradable polymer alternatives that decompose more quickly and safely in the environment and on contact with skin, eliminating the persistent carcinogenic risks associated with NTA while maintaining water conditioning benefits

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Reliability

If elevated temperatures are used in ware wash machines, then cleaning performance is improved, but energy consumption increases

Engineering Contradiction:
Improvecleaning performanceVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention changes the chemical composition parameters of the detergent to include enzymes and alternative polymers that maintain cleaning and scale prevention efficacy at lower temperatures, allowing the physical temperature parameter to be reduced while preserving performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compositions effectively reduce or eliminate scale build-up on treated surfaces, providing a safer and environmentally friendly solution while maintaining cleaning efficacy at low temperatures, thus addressing energy savings and ecological concerns.

Implementation Method 1

phosphorus-free detergent compositions which replace phosphate and/or other phosphorus containing detergent materials... use of chelating agents and/or threshold agents for use with high alkaline detergent compositions because of their ability to solubilize metal salts and/or prevent water hardness from scaling

Methodology Applied
Scientific EffectChelation:

Implementation Method 2

use of chelating agents and/or threshold agents for use with high alkaline detergent compositions because of their ability to solubilize metal salts and/or prevent water hardness from scaling and/or precipitating

Methodology Applied
Scientific EffectThreshold inhibition:

Data Source

PatentUS9394508B2Phosphorus free low temperature ware wash detergent for reducing scale build-up
Publication Date: 2016.07.19 ECOLAB USA INC
  • US9394508B2 patent drawing
  • US9394508B2 patent drawing

AI summary

Phosphorus-free detergent compositions are provided. Detergent compositions including an aminocarboxylate, water conditioning agent, source of alkalinity and water beneficially do not require the use of additional surfactants and/or polymers to provide suitable detergency and prevent scale build-up on treated surfaces. The detergent compositions are used with a sanitizer to employ the phosphorus-free detergent compositions for use as low temperature ware wash detergents that beneficially reduce scale build-up. Methods of employing the phosphorus-free detergent compositions are also provided.