Enhanced low temperature separation process

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Solution Overview

Problem

Conventional low temperature separation (LTS) processes for recovering natural gas liquids (NGL) lack selectivity in recovering valuable heavy components and require significant re-compression of light components, leading to high operating costs and inefficient NGL recovery.

Innovation Solution

An enhanced low temperature process that involves cooling a feed stream through heat exchangers, separating it in an absorber, flashing the liquid bottoms into a de-ethanizer tower, and recycling reflux streams to enhance the recovery of C3+ hydrocarbon compounds, thereby reducing the need for external refrigeration and re-compression.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional LTS processes are used to recover NGL, then the separation of light and heavy hydrocarbon components is achieved, but the selectivity in recovering valuable heavy components (C3+) is insufficient and light components require significant re-compression

Engineering Contradiction:
ImproveNGL recovery efficiencyVSAvoidre-compression energy consumption
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The process segments the hydrocarbon separation into distinct stages: initial cooling and condensation in the heat exchanger, separation in the absorber, and final fractionation in the de-ethanizer tower. This segmentation allows heavy components to be recovered selectively while light components are separated and reused as refrigerant, minimizing re-compression needs

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The de-ethanizer overhead vapor (containing light components) is condensed and the liquid is recycled back to the absorber as reflux. This feedback loop allows light components to be continuously separated and reused, reducing the need for external refrigeration and minimizing re-compression energy consumption

Inventive Principle:
Principle #23Feedback

2Ease of operation

If mechanical refrigeration systems are used in LTS processes, then cooling is provided and re-compression is reduced, but the selectivity in recovering specific NGL components cannot be controlled

Engineering Contradiction:
Improveoperating temperature controlVSAvoidcomponent recovery selectivity
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The process uses parameter changes in the form of temperature and pressure adjustments at different stages. The feed stream is cooled to specific temperatures in the heat exchanger, the absorber operates at controlled conditions, and the de-ethanizer tower uses temperature gradients to achieve selective separation of C2 from C3+ components, enabling controlled recovery of specific NGL components

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The process exploits phase transitions of hydrocarbon components at different temperatures and pressures. By controlling the temperature in the heat exchanger and absorber, and using the de-ethanizer tower to achieve phase separation, the process selectively condenses and recovers heavy components while maintaining light components in vapor phase for recycling

Inventive Principle:
Principle #36Phase transitions

3Temperature

If expansion-based cooling is used, then refrigeration is provided, but re-compression of product gas is required representing significant capital and operating expense

Engineering Contradiction:
Improvecooling temperatureVSAvoidre-compression equipment requirement
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The system uses self-service by utilizing the de-ethanizer overhead vapor (containing light components) as the refrigerant source. This vapor is condensed and recycled back to the absorber, creating a self-sustaining refrigeration cycle that eliminates the need for external expansion-based cooling systems and associated re-compression equipment

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

Instead of discarding the light components in the de-ethanizer overhead vapor, the process recovers them by condensing and recycling as refrigerant to the absorber. This recovery approach eliminates waste and removes the need for re-compression equipment while maintaining effective cooling

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves increased selectivity in recovering valuable NGL products like butane and heavier hydrocarbons while reducing operating costs by minimizing refrigerant compression and equipment size, with improved NGL product streams and reduced compressor power requirements.

Implementation Method 1

cooling the feed stream by directing the feed stream through at least one heat exchanger so as to condense at least a portion of the feed stream

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

condense at least a portion of the feed stream

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

An absorber overhead vapor stream and an absorber liquid bottoms stream are produced by separation in the absorber

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 4

flashing the absorber liquid bottoms stream into a de-ethanizer tower, thereby producing a de-ethanizer overhead vapor stream and a liquid product stream enriched in C3+ hydrocarbon compounds

Methodology Applied
Scientific EffectFlashing: Flash Evaporation

Implementation Method 5

At least a portion of the de-ethanizer overhead vapor stream is condensed to form a liquid reflux stream

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS10352616B2Enhanced low temperature separation process
Publication Date: 2019.07.16 BLACK & VEATCH CORP
  • US10352616B2 patent drawing
  • US10352616B2 patent drawing
  • US10352616B2 patent drawing

AI summary

Enhanced low temperature separation (LTS) processes are provided for separating light hydrocarbon components from heavy hydrocarbon components. The enhanced LTS process utilizes an absorber and a de-ethanizer tower to achieve sufficiently pure natural gas liquid (NGL) products and residue gas products. A portion of the de-ethanizer tower overhead is condensed and recycled as reflux for the absorber. The enhanced LTS process requires less refrigeration of the feed gas stream yet still achieves increased recovery of the valuable heavier hydrocarbons from hydrocarbon gas streams. The enhanced LTS process also reduces compression requirements compared to conventional LTS processes.