Integrated LPG Recovery via Shared Debutanizer Column

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Solution Overview

Problem

Current processes for recovering liquid petroleum gas (LPG) from refinery gas streams are inefficient, leading to significant losses due to complex and costly separation and purification steps, which increase capital and operational expenditures, and do not effectively recover LPG boiling range hydrocarbons from stripper off gases.

Innovation Solution

An integrated process that combines hydrocracking, isomerization, and transalkylation zones with the reforming zone through a debutanizer column, using a single compressor system to maximize LPG recovery by passing streams from these zones to the reforming zone, eliminating the need for separate debutanizer columns and reducing equipment requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If separate debutanizer columns and compressors are installed for each process zone (hydrocracking, isomerization, transalkylation) to recover LPG, then LPG recovery efficiency is improved, but capital expenditure and device complexity increase significantly

Engineering Contradiction:
ImproveLPG recovery efficiencyVSAvoidequipment requirements
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges the debutanizer columns and compressor systems from multiple independent process zones (hydrocracking, isomerization, transalkylation) into a single shared debutanizer column and compressor system. This consolidation allows LPG recovery functionality to be shared across all zones, reducing the total number of equipment units while maintaining recovery efficiency through centralized processing of C6- hydrocarbon streams.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The shared debutanizer column and compressor system performs multiple functions across different process zones simultaneously. The debutanizer column handles separation tasks for hydrocarbons from hydrocracking, isomerization, and transalkylation zones, while the compressor system provides compression services to multiple zones, making the equipment universal and multi-functional rather than dedicated to a single process.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If rigorous separation and purification steps are implemented to recover LPG from refinery gas streams, then LPG recovery is improved, but operational expenditure and processing time increase

Engineering Contradiction:
ImproveLPG recovery efficiencyVSAvoidprocessing time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent implements preliminary action by integrating the debutanizer column and compressor system into the process flow before streams are routed to fuel gas systems or further processing. By performing LPG recovery operations upstream in the process flow, the system captures LPG boiling range hydrocarbons before they are lost or require additional purification steps, reducing both processing time and operational expenditures.

Inventive Principle:
Principle #10Preliminary action

3Quantity of substance

If streams from hydrocracking, isomerization, and transalkylation zones are processed through separate recovery systems, then LPG recovery completeness is improved, but capital expenditure increases

Engineering Contradiction:
Improvetotal LPG recoveredVSAvoidnumber of separation machineries
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent combines the recovery systems for hydrocracking, isomerization, and transalkylation zones into a single integrated debutanizer column and compressor system. This merging allows all C6- hydrocarbon streams from the three zones to be processed through shared equipment, maintaining complete LPG recovery from each zone while eliminating the need for multiple separate recovery systems.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances LPG recovery by integrating streams across zones, reducing capital and operational expenditures, and efficiently recovering LPG from hydrocracked, isomerized, and transalkylated C6− hydrocarbons, thereby maximizing overall LPG recovery while minimizing equipment needs.

Implementation Method 1

passing at least a portion of the reformate effluent stream and at least one stream comprising C6− hydrocarbons from one or more of a hydrocracking zone, an isomerization zone, and a transalkylation zone to a debutanizer column of the reforming zone to provide a fraction comprising liquid petroleum gas (LPG)

Methodology Applied
Scientific EffectFractional distillation: Distillation

Data Source

PatentUS10899976B2Integrated process for maximizing recovery of liquid petroleum gas
Publication Date: 2021.01.26 UOP LLC
  • US10899976B2 patent drawing
  • US10899976B2 patent drawing
  • US10899976B2 patent drawing

AI summary

An integrated process for maximizing recovery of LPG is provided. The process comprises providing a hydrocarbonaceous feed comprising naphtha, and a hydrogen stream to a reforming zone. The hydrocarbonaceous feed is reformed in the reforming zone in the presence of the hydrogen stream and a reforming catalyst to provide a reformate effluent stream. At least a portion of the reformate effluent stream and at least one stream comprising C6− hydrocarbons from one or more of a hydrocracking zone, an isomerization zone, and a transalkylation zone is passed to a debutanizer column of the reforming zone to provide a fraction comprising liquid petroleum gas (LPG) and a debutanizer column bottoms stream.