Lubricating Surface Coating for High-Temperature Foil Bearings

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Solution Overview

Problem

Existing lubricating surface coatings for parts subject to high friction, such as turbomachine bearings, face issues with toxicity, limited temperature range, and inadequate wear resistance, while methods like eutectic mixtures of copper sulphide and silver do not provide satisfactory lubricating and wear resistance properties.

Innovation Solution

A method involving a heat treatment process that forms a solid network with dispersed and trapped solid carbon in the form of graphene, graphite, or amorphous carbon within an inorganic matrix, without the need for added solid lubricating fillers, using organic precursors that transform into these carbon forms during the process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a coating based on fluorocarbon compounds such as PTFE is used, then lubricating properties are improved, but toxicity to humans and environment worsens

Engineering Contradiction:
Improvelubricating propertiesVSAvoidtoxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters of the coating by using organic precursors (silanes, metal alkoxides) instead of fluorocarbon compounds. The heat treatment temperature parameter (200-500°C) transforms these precursors into a coating with lubricating properties while eliminating toxicity issues associated with PTFE.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating structure consisting of an inorganic matrix (from metal oxide precursors) combined with organic groups (from silane or metal alkoxide precursors). This composite structure provides both lubricating properties and environmental compatibility, replacing the homogeneous fluorocarbon coating structure.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a coating based on fluorocarbon compounds such as PTFE is used, then lubricating properties are improved, but maximum operating temperature is limited to 200-250°C

Engineering Contradiction:
Improvelubricating propertiesVSAvoidmaximum operating temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The composite structure combining inorganic matrix (metal oxides) with organic groups creates a coating that maintains lubricating properties at higher temperatures. The inorganic component provides thermal stability while the organic component contributes to lubrication, enabling operation above 250°C unlike pure PTFE coatings.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The heat treatment temperature parameter (200-500°C) during coating formation creates a structurally different material than simple deposition. This thermal processing transforms the precursor molecules into a cross-linked network that withstands higher operating temperatures while retaining lubricating characteristics.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If eutectic mixture based on copper and silver sulfide is used, then manufacturing process is simplified, but lubricating and wear-resistant properties are insufficient

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidlubricating and wear-resistant properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention uses standard heat treatment temperatures (200-500°C) that are commonly available in manufacturing, avoiding the need for specialized low-temperature processes. The resulting coating properties (lubrication and wear resistance) significantly exceed those of copper-silver sulfide eutectic mixtures while maintaining manufacturing simplicity.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If solid lubricating fillers are added to the coating, then lubricating properties are improved, but risk of filler release over time increases

Engineering Contradiction:
Improvelubricating propertiesVSAvoidfiller release
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The coating generates its own lubricating properties through the intrinsic structure formed during heat treatment. The organic groups within the inorganic matrix provide lubrication without requiring external solid filler additives, eliminating the risk of filler release while maintaining reliable lubricating performance.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The integrated composite structure where organic groups are chemically bound within the inorganic matrix prevents any substance release. Unlike physical mixtures of fillers and binders, the chemical integration ensures both lubricating properties and complete retention of all coating components during service.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting coating exhibits excellent lubrication and wear resistance at high speeds and temperatures, suitable for use in aircraft air conditioning systems and other high-stress environments, with improved safety and environmental compatibility.

Implementation Method 1

heat treatment is carried out at a temperature lower than the total decomposition temperature of the lubricating allotropic forms of solid carbon, in particular so as to form within said solid network at least one lubricating solid carbon compound selected from the group consisting of graphene, graphite, amorphous carbon, and mixtures thereof

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentEP2988882B1Process for manufacturing a part provided with a lubricating surface coating, part provided with such a coating and turbomachine
Publication Date: 2021.06.16 LIEBHERR AEROSPACE TOULOUSE
  • EP2988882B1 patent drawingFigure 1~2
  • EP2988882B1 patent drawingFigure 3~4
  • EP2988882B1 patent drawingFigure 5~6

AI summary

The invention relates to a process for manufacturing a part provided with a lubricating surface coating (10), in which: a composition is prepared that comprises at least one precursor having at least one organic group, said composition is deposited on the part, a heat treatment is carried out, characterized in that said heat treatment of said coating is carried out at a temperature above 220°C, so as to form a lubricating surface coating (10) formed of an at least partially inorganic solid network incorporating solid carbon in at least one lubricating allotropic form in the dispersed state and trapped within said solid network. The invention also relates to a part, such as a foil of a foil bearing (1) obtained by said process, a turbomachine, such as a turbomachine for a fuel cell, comprising such a part, and an aircraft cabin air-conditioning system comprising at least one such turbomachine.