Plasticizer-Free Laminates with Luminophore Interlayers

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Solution Overview

Problem

Conventional laminated glazing units (LGUs) often rely on plasticized thermoplastic materials for their interlayers, which, while providing good glass adhesion and optical clarity, raise concerns about the use of plasticizers.

Innovation Solution

A laminate comprising a first and second optically transparent sheet with an interlayer that includes structural support layers and polymeric layers, where at least one polymeric layer contains a luminophore and is made of thermoplastic polyurethane, and the interlayer is substantially free of plasticizers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If plasticized thermoplastic materials are used in the interlayer, then glass adhesion and optical clarity are improved, but harmful factors associated with plasticizers are introduced

Engineering Contradiction:
Improveglass adhesionVSAvoidplasticizer harmful effects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent removes plasticizers from the interlayer composition entirely, extracting the harmful component while retaining the essential adhesive and optical properties through alternative polymer formulations such as polyvinyl butyral, polyvinyl formal, or ionomeric polymers without plasticizer additives

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters of the interlayer by selecting polymers with inherently suitable adhesive properties and optical clarity without requiring plasticizers, thereby altering the material parameters to eliminate harmful effects while maintaining performance

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional thermoplastic interlayers are used, then manufacturing simplicity is maintained, but mechanical strength and impact resistance are insufficient

Engineering Contradiction:
Improveinterlayer processingVSAvoidimpact resistance
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent employs composite interlayer structures combining multiple polymer types or layers (e.g., polyvinyl butyral with ionomeric polymer, or multi-layer configurations) that synergistically provide both ease of manufacture through conventional lamination processes and enhanced mechanical strength and impact resistance through the composite architecture

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If plasticized thermoplastic materials are used, then optical clarity is achieved, but durability is compromised

Engineering Contradiction:
Improveoptical clarityVSAvoiddurability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent extracts plasticizers from the interlayer formulation, eliminating the source of durability degradation while maintaining optical clarity through alternative polymer selections that inherently provide both optical transparency and long-term durability without plasticizer-induced degradation

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laminate achieves improved mechanical strength, impact resistance, and optical properties such as high light transmission and quantum yield, while eliminating the potential drawbacks associated with plasticizers.

Implementation Method 1

A first polymeric layer of the one or more polymeric layers may include a luminophore

Methodology Applied
Scientific EffectLuminescence: Luminescence

Implementation Method 2

the luminophore may include one or more of an organic phosphorescent molecule, a quantum dot, an organic dye, a fluorophore

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS20250091329A1Laminates and interlayers thereof and methods for the same
Publication Date: 2025.03.20 DELSTAR TECHNOLOGIES INC
  • US20250091329A1 patent drawing
  • US20250091329A1 patent drawing
  • US20250091329A1 patent drawing

AI summary

Laminates and interlayers thereof are provided. The laminates may include a first optically transparent sheet, a second optically transparent sheet, and an interlayer. The interlayer may be interposed between the first and second optically transparent sheets, and may couple the first and second optically transparent sheets with one another. The interlayer may include one or more structural support layers and one or more polymeric layers. A first polymeric layer of the one or more polymeric layers may include a luminophore. The interlayer may be substantially free of plasticizers.