LVT Inorganic Encapsulation for OLED Moisture Resistance

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Solution Overview

Problem

Organic light-emitting display apparatuses are vulnerable to external moisture and heat, making it difficult to enhance their durability and encapsulation characteristics using traditional sputtering methods.

Innovation Solution

A thin film encapsulating layer made of low temperature viscosity transition (LVT) inorganic materials, including tin oxide and compounds like boron oxide, bismuth oxide, barium oxide, and ammonium dihydrogen phosphate, is applied using a sputtering process, with a viscosity transition temperature lower than the metamorphic temperature of the intermediate layer, to provide enhanced encapsulation and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a sputtering method is used to form the encapsulating structure, then the manufacturing process can be implemented, but the encapsulation characteristics and durability cannot be sufficiently increased

Engineering Contradiction:
Improveencapsulation characteristicsVSAvoiddifficulty to form encapsulating structure
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the material parameters by using LVT inorganic materials with specific viscosity transition temperatures (lower than the metamorphic temperature of the intermediate layer). This parameter change enables the material to flow and self-heal at processing temperatures, resolving the contradiction between manufacturability and encapsulation quality by allowing standard sputtering processes to produce superior encapsulation structures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite inorganic materials containing LVT components (such as bismuth oxide, boron oxide, or barium oxide combined with other metal oxides). These composite materials combine the benefits of low-temperature viscosity transition with the protective properties of inorganic encapsulation layers, enabling effective encapsulation while maintaining compatibility with existing sputtering manufacturing processes.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If the viscosity transition temperature of the LVT inorganic material is kept low to enable flowability, then encapsulation quality improves, but the material may react with moisture and foreign substances

Engineering Contradiction:
Improveflowability of LVT inorganic materialVSAvoidreactivity with moisture
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent carefully controls the viscosity transition temperature parameter to be below the metamorphic temperature of the intermediate layer but above operating temperatures. This precise parameter control ensures the material remains stable during device operation while becoming flowable only during the encapsulation process, preventing moisture reactions during normal use while enabling self-healing during manufacturing.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates an inert environment by forming the encapsulating structure in a controlled atmosphere during manufacturing, preventing moisture and foreign substances from contacting the LVT inorganic material during the low-temperature processing stage. This inert environment protection eliminates reactivity issues while maintaining the flowability benefits.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The LVT inorganic material encapsulating layer effectively prevents moisture and thermal damage, increasing the durability and encapsulation characteristics of the organic light-emitting display apparatus while suppressing reactivity with moisture and foreign substances.

Implementation Method 1

a low temperature viscosity transition (LVT) inorganic material... A viscosity transition temperature of the LVT inorganic material may be a minimum temperature capable of providing a flowability to the LVT inorganic material

Methodology Applied
Scientific EffectViscosity transition:

Implementation Method 2

One of methods for forming the encapsulating structure is a sputtering method which uses a sputtering target... The thin film encapsulating layer includes at least one inorganic film including a low temperature viscosity transition (LVT) inorganic material

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 3

there may be a need for an encapsulating structure that encapsulates the organic light-emitting device... The thin film encapsulating layer may cover a top surface and a side of the organic light-emitting device

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentUS9490449B2Organic light-emitting display apparatus and method for manufacturing the same
Publication Date: 2016.11.08 SAMSUNG DISPLAY CO LTD
  • US9490449B2 patent drawing
  • US9490449B2 patent drawing
  • US9490449B2 patent drawing

AI summary

An organic light-emitting display apparatus includes: a substrate, and an organic light-emitting device disposed on the substrate. The organic light-emitting device includes a first electrode, a second electrode, and an intermediate layer including at least an organic emission layer. In addition, the organic light-emitting display apparatus further includes a thin film encapsulating layer disposed on the organic light-emitting device. The thin film encapsulating layer includes at least one inorganic film including a low temperature viscosity transition (LVT) inorganic material. The LVT inorganic material includes tin oxide and at least one of boron oxide (B2O3), bismuth oxide (Bi2O3), barium oxide (BaO), and ammonium dihydrogen phosphate (NH4H2PO4).