Macro-Cement Coating for UHPC Particle Dispersion

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Solution Overview

Problem

Current methods for producing ultra-high performance concrete (UHPC) face challenges in achieving uniform distribution of silica fume and nano-particles due to aggregation, leading to reduced strength and durability, and existing mixing technologies fail to provide optimal homogenization and shelf life of cementitious materials.

Innovation Solution

A multicomponent macro-cement composition is developed, comprising micron-sized cementitious materials coated or loaded with submicron or nano-sized supplemental cementitious materials, along with pozzolanic materials and reinforcement fibers, using a multi-stage homogenization process that includes high-energy mixing and mechanical activation to achieve uniform distribution and enhanced properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If silica fume and nano-particles are added to cementitious materials to improve packing density and strength, then the compressive strength and durability are enhanced, but particle aggregation occurs leading to non-uniform distribution

Engineering Contradiction:
Improvecompressive strengthVSAvoiduniform distribution of particles
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by pre-coating silica fume and nano-particles onto cementitious carrier particles before final mixing. This pre-attachment prevents aggregation during storage and handling, ensuring uniform distribution when the macro-cement is later used in concrete applications.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses an intermediary approach by employing carrier particles (cementitious materials) as intermediaries to hold and distribute the silica fume and nano-particles. These carriers act as mediators that prevent direct aggregation of fine particles while maintaining their beneficial effects on strength and durability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If high-energy mixing is used to achieve uniform particle distribution, then homogenization is improved, but particle aggregation may increase due to mechanical activation

Engineering Contradiction:
ImprovehomogenizationVSAvoidparticle distribution stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary action by pre-attaching particles through coating before high-energy mixing occurs. This pre-bonding prevents aggregation during subsequent mechanical activation and mixing processes, maintaining stability throughout the concrete production cycle.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies parameter changes by controlling the energy input at different stages - using lower energy during coating to prevent aggregation, then allowing higher energy mixing later to achieve homogenization without disrupting the pre-formed particle attachments.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If multi-stage homogenization process is implemented to improve shelf life and uniformity, then process complexity increases, but production time and energy consumption increase

Engineering Contradiction:
Improveshelf lifeVSAvoidproduction time
Core Design Contradiction:
Duration of action of stationary objectVSLoss of time

Solution Approach 1:

The patent applies preliminary action by performing particle coating and attachment during the cement manufacturing process itself, before the macro-cement is stored or shipped. This eliminates the need for separate pre-mixing stages later, reducing overall production time while extending shelf life through stable pre-formed structures.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the coating process with the existing cement manufacturing process, combining what would otherwise be separate operations into a single integrated workflow. This reduces total process time and energy consumption while achieving the benefits of multi-stage homogenization.

Inventive Principle:
Principle #5Merging (Combining)

4Quantity of substance

If micron-sized cementitious particles are used as carriers, then packing density is improved, but handling and dust generation become more difficult

Engineering Contradiction:
Improvepacking densityVSAvoiddust handling hazards
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent applies this principle by forming a coating layer (thin film) of silica fume and nano-particles on the carrier particles. This coating acts as a protective shell that reduces dust generation during handling while maintaining the high packing density benefits of the fine particles.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent creates composite macro-cement particles combining cementitious carriers with silica fume and nano-particle coatings. This composite structure maintains high packing density while the coated surface reduces dust generation and improves handling characteristics compared to bare fine particles.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in improved packing density, increased strength, extended shelf life, and enhanced workability of UHPC, overcoming aggregation issues and optimizing the distribution of particles, leading to superior mechanical properties and reduced dust handling hazards.

Implementation Method 1

The multi-stage homogenization process is characterized in that the macro-cement is homogenized in water at high energy levels, in subsequent process steps homogenized as a mixture at lower energy levels

Methodology Applied
Scientific EffectHomogenization:

Implementation Method 2

utilizing a multi-stage process involving mechanical activation and homogenization of the macro-cement at various energy levels

Methodology Applied
Scientific EffectMechanical activation:

Implementation Method 3

comprising micron-sized cementitious materials coated or loaded with submicron or nano-sized supplemental cementitious materials

Methodology Applied
Scientific EffectCoating: Coatings

Data Source

PatentUS11148972B2Macro-cement compositions, method of producing macro-cement and engineered forms of macro-cement, and multi-stage homogenization process for preparing cement based materials
Publication Date: 2021.10.19 MACROCEMENT IND LTD
  • US11148972B2 patent drawing
  • US11148972B2 patent drawing
  • US11148972B2 patent drawing

AI summary

A macro-cement and associated methods useful for preparing pastes, mortars, concretes and other cement-based materials having high workability, high density, and high strength are disclosed. A method of producing a macro-cement includes cement, supplemental cementitious materials (SCM's), including siliceous submicron-sized particles and nano-sized particles, and polymers in the form of liquid or dry chemical admixtures for concrete. The cement mixture may be used for making ultra-high performance concrete (UHPC).