Marine Macroalgae Recovery of Rare Earths From Saline Effluents
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Solution Overview
Problem
Existing technologies lack optimal conditions and parameters for efficiently recovering rare earth elements (REEs) and Lithium from aqueous media, particularly industrial effluents, using living macroalgae, which is crucial for industrial-scale processes.
Innovation Solution
A process involving the use of living marine macroalgae to interact with an aqueous medium, followed by separation and processing to obtain a secondary medium enriched with REEs and/or Lithium, utilizing forced circulation and dissolution agents, and optionally magnetic nanomaterials for enhanced separation.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If living marine macroalgae are used to recover REEs and Lithium from aqueous media, then recovery efficiency is improved, but optimal processing conditions and parameters are not established
Solution Approach 1:
The patent systematically optimizes critical process parameters including pH (maintained between 6-9), salinity (5-35 g/L), temperature (15-30°C), and macroalga concentration (0.1-10 g/L) to maximize REE and Lithium recovery efficiency. This parameter optimization enables consistent high-efficiency recovery while providing clear operational guidelines for industrial implementation
2Object-affected harmful factors
If macroalgae are used for REE recovery from industrial effluents, then environmental compliance is improved, but system complexity increases
Solution Approach 1:
The patent employs living marine macroalgae that autonomously perform multiple functions: they grow and accumulate REEs and Lithium from effluents, then can be harvested and processed to recover the metals. The system requires minimal external intervention beyond initial setup, with the macroalgae self-regulating their uptake based on environmental conditions, thereby reducing operational complexity while ensuring environmental compliance
Solution Approach 2:
The macroalga system serves multiple functions simultaneously: it treats industrial effluents by removing toxic metals, recovers valuable REEs and Lithium, and can be processed to produce a secondary medium enriched with recovered elements. This multi-functionality consolidates what would otherwise require separate treatment and recovery systems into a single integrated process
3Productivity
If living marine macroalgae are deployed for element recovery, then recovery effectiveness is improved, but system dimensions and scale requirements increase
Solution Approach 1:
The patent creates localized high-concentration zones of macroalgae within the aqueous medium, particularly in recovery dispositions where effluent contacts the macroalgae. This localized concentration strategy achieves high recovery effectiveness in specific zones rather than requiring uniform distribution throughout large volumes, thereby reducing overall system dimensions while maintaining productivity
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
Achieves efficient recovery of REEs and Lithium with reduced environmental impact, meeting regulatory discharge standards and enabling scalable, high-efficiency systems with reduced system complexity and dimensions.
Implementation Method 1
The document JPH0283093 (A) discloses a method of purification of industrial effluents using chlorophyceae of the genre unicellular chlamydomonas for sorption of heavy metals, such as Cu, Ni or similar, from said industrial effluent.
Implementation Method 2
The document ES 2251286 A1 discloses a system of treatment of residual waters including filamentous green macroalgae of the genres Hydrodictyon or Cladophora, capable of absorbing and recycling nutrients and/or fixating/capturing heavy metals
Implementation Method 3
A process involving the use of living marine macroalgae to interact with an aqueous medium, followed by separation and processing to obtain a secondary medium enriched with REEs and/or Lithium, utilizing forced circulation and dissolution agents
Implementation Method 4
processing the separated quantity of living marine macroalgae so as to obtain a secondary medium that includes quantities of REEs and/or Lithium
Data Source
AI summary
The present invention refers to processes and systems of recovery of rare earth elements and/or Lithium, from a certain type of primary salted medium such as a solid medium, such as muds, or such as an aqueous medium of high salinity, in particular from aqueous media with a pH greater than 6, and based upon certain types of living marine macroalgae.


