Magnesium Battery Electrolyte for Stable Deposition and Low Overpotential

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Solution Overview

Problem

The electrolytic solution for magnesium batteries suffers from poor interfacial stability, high susceptibility to impurities, and ineffective magnesium ion conduction, leading to high charging and discharging over-potential, non-uniform deposition-dissolution, and potential short-circuit issues.

Innovation Solution

An electrolytic solution comprising a non-aqueous solvent such as imidazole ionic liquids, pyrrole ionic liquids, or ether compounds, combined with an electrolyte salt of the formula [MgmLinXo(HMDS)2m+n−oRp]·Mq, which provides good stability, water resistance, and impurity resistance, promoting reversible magnesium deposition-dissolution and reducing over-potential.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic solvents and magnesium salts are used in the electrolytic solution, then the electrolytic solution can conduct magnesium ions, but the magnesium ions react with the solvents and salts to form a passivation layer on the magnesium metal surface, impeding ion conduction and causing interfacial instability

Engineering Contradiction:
Improveinterfacial stabilityVSAvoidpassivation layer formation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a specially designed electrolyte salt with a unique molecular structure that acts as an intermediary between magnesium ions and the solvent. This electrolyte salt forms a stable interfacial layer that prevents direct reaction between magnesium metal and conventional solvents, thereby eliminating passivation layer formation while maintaining ion conduction. The electrolyte salt serves as a protective mediator that resolves the contradiction between ion conduction and interfacial stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the electrolyte by using a novel electrolyte salt with specific molecular structure and composition. This parameter change transforms the electrolytic solution from one that forms passivation layers to one that maintains stable interfaces while conducting magnesium ions effectively.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the electrolytic solution interface is unstable and susceptible to impurities, then the battery experiences high charging and discharging over-potential and non-uniform deposition-dissolution, but improving interface stability requires avoiding conventional solvents that react with magnesium

Engineering Contradiction:
Improvecharging-discharging performanceVSAvoidimpurity susceptibility
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The electrolyte salt acts as an intermediary protective layer at the electrode-electrolyte interface, shielding the magnesium metal from impurities such as water, oxygen, and carbon dioxide. This intermediary layer prevents impurity-induced interface instability while enabling smooth magnesium ion deposition and dissolution, thereby reducing over-potential and improving charging-discharging performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the harmful effect of impurity susceptibility into a benefit by using the electrolyte salt to create a protective interface. The electrolyte salt's molecular structure is designed to be more susceptible to impurities than magnesium metal, effectively sacrificing itself to protect the magnesium electrode, thereby converting the harm of impurity exposure into a protective mechanism.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Productivity

If conventional electrolytic solutions are used, then magnesium ion conduction is possible, but the solutions cannot conduct magnesium ions effectively during long-time charging and discharging, leading to battery failure

Engineering Contradiction:
Improvemagnesium ion conduction efficiencyVSAvoidbattery cycling life
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent ensures continuous and stable magnesium ion conduction throughout the battery's operational life by using an electrolyte salt that maintains stable solvation structures. The electrolyte salt enables uninterrupted magnesium ion transport during long-time charging and discharging cycles, preventing the degradation and failure that occur with conventional electrolytic solutions.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent uses a composite electrolytic solution system consisting of conventional solvents combined with a novel electrolyte salt. This composite approach leverages the good ion solvation ability of conventional solvents while adding the stability and protection provided by the specially designed electrolyte salt, achieving both efficient ion conduction and long cycling life.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the charging-discharging specific capacity and cycling stability of magnesium batteries, while maintaining stability and resistance to impurities, thereby improving the overall performance and longevity of the batteries.

Implementation Method 1

promoting reversible magnesium deposition-dissolution and reducing over-potential

Methodology Applied
Scientific EffectElectrochemical reactions: Redox Reactions

Implementation Method 2

comprising a non-aqueous solvent and an electrolyte salt

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS20250132390A1Electrolytic solution for magnesium batteries, method for preparing the same, and magnesium batteries
Publication Date: 2025.04.24 TSINGHUA UNIVERSITY
  • US20250132390A1 patent drawing
  • US20250132390A1 patent drawing
  • US20250132390A1 patent drawing

AI summary

The present application provides an electrolytic solution for magnesium batteries, a method for preparing the same, and a magnesium battery, comprising a non-aqueous solvent and an electrolyte salt, wherein the non-aqueous solvent is selected from one or more of imidazole ionic liquids, pyrrole ionic liquids, piperidine ionic liquids, ether compounds, ester compounds, pyridine compounds, nitrile compounds, sulfone compounds, or ketone compounds; the electrolyte salt has a chemical formula [MgmLinXo(HMDS)2m+m−oRp]·Mq. The electrolytic solution for magnesium batteries provided by the present application is endowed with good stability, strong water resistance and impurity resistance, and excellent electrochemical performance under the mutual synergistic effect among the components, and excellent electrochemical performance under the mutual synergistic effect among the components, and at the same time, the electrolytic solution can promote reversible deposition-dissolution of magnesium, reduce the over-potential, inhibit formation of a passivation layer of magnesium salts on the surface of the anode, and increase the charging-discharging specific capacity and cycling stability of the magnesium battery.