Magnesium Detergent Lubricant Reduces Diesel Filter Clogging

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Low-SAPS lubricating oil compositions struggle to reduce diesel particulate filter clogging without compromising the basicity of the lubricating oil, which is essential for neutralizing acidic by-products of combustion and controlling engine wear.

Innovation Solution

Incorporating magnesium detergents, such as magnesium salicylate, magnesium phenate, or magnesium sulphonate, in lubricating oil compositions to reduce sulphated ash content while maintaining or exceeding the basicity requirements, thereby minimizing filter clogging in diesel particulate filters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If the amount of detergent is reduced to reduce sulphated ash content, then the clogging effect on diesel particulate filter is reduced, but the basicity (TBN) of the lubricating oil composition is compromised

Engineering Contradiction:
Improveclogging effect on diesel particulate filterVSAvoidbasicity (TBN) of lubricating oil composition
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by replacing traditional calcium-based detergents with magnesium-based detergents. This substitution maintains the required TBN levels while producing lower sulphated ash content, thereby resolving the contradiction between maintaining basicity and reducing filter clogging

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite detergent formulations combining magnesium-based detergents with specific additives including zinc dialkyldithiophosphates, boron compounds, and nitrite corrosion inhibitors. This composite approach achieves both adequate TBN and reduced sulphated ash content

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If the sulphated ash content is reduced to minimize filter clogging, then the diesel particulate filter life is extended, but the ability to neutralize acidic by-products is reduced

Engineering Contradiction:
Improvediesel particulate filter lifeVSAvoidacidic by-products neutralization capability
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the chemical parameters by using magnesium-based detergents that provide high TBN contribution per unit of sulphated ash. This allows the formulation to achieve both extended filter life through reduced sulphated ash and maintained acidic by-products neutralization through adequate TBN levels

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of magnesium detergents in lubricating oil compositions effectively reduces diesel particulate filter clogging, as measured by the VW diesel particulate filter test, while maintaining the necessary basicity to neutralize acidic by-products, thus extending filter life and reducing fuel consumption.

Implementation Method 1

Total Base Number (TBN) is a measure of how well a lubricating oil composition can neutralise acidic by-products of combustion/oxidation

Methodology Applied
Scientific EffectNeutralization reaction: Redox Reactions

Implementation Method 2

Sulphated ash is the total weight percent of residue remaining after a lubricating oil composition has been carbonised, and the residue subsequently treated with sulphuric acid and heated to constant weight

Methodology Applied
Scientific EffectSulphated ash formation reduction: Precipitation

Data Source

PatentEP1788068B1Use of a magnesium detergent in a lubricating oil composition
Publication Date: 2015.09.16 SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV
  • EP1788068B1 patent drawing

AI summary

The use, in a lubricating oil composition comprising base oil, of one or more magnesium detergents, for the reduction of clogging in a diesel particulate filter.