Magnesium Hydroxide Colloids for Sludge Separation

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Solution Overview

Problem

Industrial wastewater sludges are challenging to separate due to the low density of particulates and accumulated spent flocculants, combined with high dissolved solids, leading to poor separation efficiency in traditional methods like Dissolved Nitrogen Floatation (DNF) units.

Innovation Solution

The addition of insoluble magnesium hydroxide colloidal suspensions to industrial sludges destabilizes colloidal particles, allowing for effective separation through sedimentation, flocculation, filtration, or centrifugation by increasing the density of flocculents and promoting the formation of larger agglomerates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional coagulants and flocculants are used to separate sludge particles, then some separation occurs, but separation efficiency remains poor due to low density of particulates and spent flocculants combined with high dissolved solids

Engineering Contradiction:
Improveseparation efficiencyVSAvoidseparation quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the density parameter of the sludge system by adding high-density materials (metal oxides, metallurgical by-products, or dense flocculants) to the mixture. This density modification causes the low-density spent flocculants and particulates to separate and float to the top, while the high-density added materials sink to the bottom, creating distinct layers that improve separation efficiency and quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material systems by combining traditional flocculants with high-density materials (such as metal oxides or metallurgical by-products). This composite approach creates a multi-component system where different materials perform different functions: the flocculant aggregates particles while the high-density material provides ballast for effective settling and separation, overcoming the limitations of single-material approaches

Inventive Principle:
Principle #40Composite materials

2Productivity

If dissolved nitrogen floatation is used to separate particulate matter, then floating solids are removed, but the bottom sludge and top float require further treatment and combination

Engineering Contradiction:
Improveclarification efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies density modification to the combined bottom sludge and top float from DNF units. By adding high-density materials to this combined stream, the system creates density differences that enable further separation, allowing effective solids-liquid separation in subsequent processing steps and reducing the need for additional complex treatment operations

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high dosing rates of coagulants are used to overcome poor separation, then separation improves, but treatment cost and chemical consumption increase

Engineering Contradiction:
Improveseparation qualityVSAvoidcoagulant dosage
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent creates a composite system combining flocculants with high-density materials (metal oxides, metallurgical by-products, or dense flocculants). This composite approach allows the flocculant to perform particle aggregation while the high-density component provides ballast for settling, achieving effective separation at lower overall chemical dosing rates compared to using high quantities of traditional coagulants alone

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The high-density material acts as an intermediary that facilitates separation by providing density contrast. It mediates between the low-density spent flocculants and the liquid phase, enabling effective separation without requiring excessive amounts of traditional coagulants, thus reducing chemical consumption and treatment cost

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the separation of sludges in DNF, Dissolved Air Flotation (DAF), and American Petroleum Institute Separator (API) processes, enabling the recovery of components and reducing waste volume by facilitating the settling of solids and separation of water and oil components.

Implementation Method 1

adding an insoluble magnesium hydroxide colloidal suspension into the industrial sludge to destabilize the industrial sludge

Methodology Applied
Scientific EffectCoagulation: Coagulation

Implementation Method 2

adding insoluble magnesium hydroxide colloidal suspension into the sludge prior to physically separating components of the sludge

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 3

separating destabilized components of the industrial sludge

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Data Source

PatentUS11306015B2Treatment of sludges and flocculants using insoluble mineral colloidal suspensions
Publication Date: 2022.04.19 HERITAGE RESEARCH GROUP LLC

AI summary

A method of separating sludge which involves adding an insoluble mineral colloidal suspension into an industrial sludge to destabilize the industrial sludge and separating destabilized components of the industrial sludge. The insoluble mineral colloidal suspension includes magnesium hydroxide. In an alternative embodiment dry finely divided magnesium hydroxide can be added and then dispersed into an industrial sludge. Conventional flocculants and/or coagulants can also be added. Conventional physical separation processes can be used to separate the destabilized industrial sludge.