Magnetic Carrier Surface Roughness for Electrophotographic Developer

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Solution Overview

Problem

Conventional magnetic carriers for electrophotographic developers face issues with peeling-off of resin coatings due to abrasion and mechanical stress, leading to unstable electrification and poor image quality, particularly in high-speed and high-grade printing applications.

Innovation Solution

The development of spherical magnetic composite particles with a phenol resin binder and ferromagnetic iron oxide particles, featuring controlled surface irregularities and a melamine resin coating, which enhances adhesion, durability, and electric resistance stability, reducing voltage dependency and maintaining high-quality image gradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the surface of the carrier is coated with resin to prevent spent toner, then the charging property is improved, but the coating layer peels off due to friction and mechanical stress

Engineering Contradiction:
Improvecharging property stabilityVSAvoidcoating layer adhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention creates local quality differences on the carrier surface by forming protrusions with specific roughness (Rz: 0.05-2.0 μm) in certain areas while maintaining smooth areas elsewhere. This local surface variation enhances coating adhesion at the protrusion sites through mechanical interlocking, preventing peeling while preserving charging properties in smooth areas.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention performs preliminary action by pre-forming the surface protrusions and controlling surface roughness before applying the resin coating. This preliminary surface preparation ensures that the coating adheres properly from the start, preventing subsequent peeling under friction and mechanical stress during developer operation.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If the carrier undergoes repeated frictional contact with toner, then the charging property is improved through electrification, but the surface conditions deteriorate leading to spent toner

Engineering Contradiction:
Improveelectrification performanceVSAvoidcarrier service life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention changes the surface roughness parameter (Rz: 0.05-2.0 μm) and protrusion density parameters to optimize both electrification performance and service life. The controlled surface parameters allow sufficient toner contact for charging while preventing excessive wear and spent toner formation through appropriate mechanical stress distribution.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite surface structure combining protrusions and smooth areas, effectively a composite topography, that provides both the mechanical contact needed for electrification and the durability to prevent spent toner. The dual-zone surface acts as a composite functional structure.

Inventive Principle:
Principle #40Composite materials

3Strength

If the resin coating layer is made thicker to prevent peeling, then the adhesion is improved, but the electric resistance becomes too high causing poor image density

Engineering Contradiction:
Improvecoating layer adhesionVSAvoidelectric resistance control
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention applies local quality by concentrating the coating thickness enhancement at protrusion sites where adhesion is critical, while maintaining thinner coating at smooth areas to preserve electric resistance properties. This localized approach allows sufficient adhesion without excessive overall resistance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention uses partial action by applying the resin coating selectively thicker at specific locations (protrusions) rather than uniformly across the entire surface. This partial enhancement provides sufficient adhesion at critical points without the excessive overall thickness that would cause high electric resistance and poor image density.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a magnetic carrier with improved durability and stability, preventing peeling-off and maintaining adequate electric resistance, enabling high-quality, long-lasting images with excellent gradation and reduced voltage dependency.

Implementation Method 1

delivering the toner into a developing zone near the surface of the photosensitive member on which the latent image is formed, by a developing sleeve in which magnets are accommodated, using a magnetic force thereof

Methodology Applied
Scientific EffectMagnetic force: Magnetism

Implementation Method 2

The carrying particles called a magnetic carrier acts for imparting an appropriate positive or negative electric charge amount to the toner by frictional electrification

Methodology Applied
Scientific EffectFrictional electrification: Triboelectric Effect

Data Source

PatentUS9606467B2Magnetic carrier for electrophotographic developer and process for producing the same, and two-component system developer
Publication Date: 2017.03.28 TODA KOGYO CORP
  • US9606467B2 patent drawing
  • US9606467B2 patent drawing
  • US9606467B2 patent drawing

AI summary

The present invention relates to a magnetic carrier for an electrophotographic developer comprising spherical magnetic composite particles comprising a phenol resin as a binder and ferromagnetic iron oxide particles bonded to each other through the phenol resin, wherein the spherical magnetic composite particles have a ten-point mean roughness Rz of 0.3 to 2.0 μm. The magnetic carrier for an electrophotographic developer according to the present invention exhibits an excellent durability against peeling-off and abrasion of coating resins formed thereon and a high stability to mechanical stress exerted onto the carrier, is free from occurrence of spent toner, can be stably held over a long period of time without occurrence of fogging and unevenness in density of toner images, and can keep high-quality images with an excellent gradation for a long period of time.